Chemical Engineering Science, Vol.58, No.3-6, 1071-1077, 2003
High temperature fluidized bed reactor: measurements, hydrodynamics and simulation
This paper was made possible through the development of a novel high temperature optical fiber probe to study the hydrodynamics of a high temperature fluidized bed reactor. The experimental results show that the hydrodynamic parameters considerably change with bed temperature when fluidizing FCC particles. For a given superficial gas velocity, the average local particle concentration, the dense phase fraction and the particle concentration in the dense phase decrease with increasing bed temperature. As a result of an increase in temperature, the fluidized behavior of the FCC particles progressively shifts from typical Geldart A towards B. Consequently, a modified two-phase model, based on the simple two-phase model, integrating the effects of temperature and superficial gas velocity on the hydrodynamics, is proposed. Simulation of a reactive catalytic system using a conventional simple two-phase model and the modified model is achieved. The predicted reactor performances strongly differ for each model. In the present case, the simple two-phase model underestimates the reactor performance by inadequately accounting for the solid fractions in the bubble and dense phases and their dependence on temperature and superficial gas velocity. This suggests that the hydrodynamic models should take into account the effects of temperature and superficial gas velocity when simulating the performance of a high temperature fluidized bed reactor. (C) 2003 Elsevier Science Ltd. All rights reserved.
Keywords:fluidized bed reactor;high temperature;novel optical fiber probe;hydrodynamics;two-phase model;reactor simulation