A new ab initio potential energy surface (PES) for the H+N2O-->OH+N-2 reaction has been constructed using the GROW package of Collins and co-workers. The ab initio calculations have been done using the Becke three-parameter nonlocal exchange functional with the nonlocal correlation of Lee, Yang, and Parr density functional theory. A detailed quasiclassical trajectory study of integral and differential cross sections, product rovibrational populations, and internal energy distributions on the new PES is presented. The theoretical integral cross sections as a function of collision energy are in qualitative agreement with the experimental measurements. A good correspondence is found between the calculated OH(v' = 0,1) rovibrational populations and the recent measurements of Brouard and co-workers at 1.48 eV collision energy. In particular, the calculated kinetic energy release distributions for state resolved OH(v',N') products predict a substantial fraction of total energy going into rotational excitation of the N-2 co-product, in good agreement with the experimental findings. (C) 2003 American Institute of Physics.