Catalysis Letters, Vol.86, No.4, 235-243, 2003
Further studies on oscillations over nickel wires during the partia oxidation of methane
Oscillatory reactions over nickel wires during the partial oxidation of methane were investigated in a tubular continuous flow reactor made of quartz at atmospheric pressure. A modified thermocouple was designed to measure the temperature while the interposed nickel coil worked as a catalyst. Significant effects on the oscillations were observed by varying the system temperature and the feed gas composition, and by cutting off one of the reactant gases temporarily.