For reducing amount of CO2 emitted by acetylene production, a research on energy efficient plasma technologies for converting methane to acetylene was conducted, resulting in development of a tubular circle-to-plate (CTP) type of reactor. The CTP reactor driven by a pulsed plasma converted mixture of methane and CO2 to acetylene, ethylene, ethane, carbon monoxide, higher hydrocarbons such as C-3 and C-4, and hydrogen. CO2 was used mainly for stabilizing the plasma discharge, though it also reacted with methane yielding CO and hydrogen. A maximum energy efficiency of 4 mmol/kJ, which was obtained at a pulse frequency of 625 Hz, indicated a potential to reduce CO2 emission from the acetylene production. The energy efficiency decreased at a pulse frequency above 625 Hz with the CTP reactor, which differed from results with co-axial cylindrical (CAC) and point-to-point (PTP) type reactors. Acetylene selectivity was 62% at maximum at 8 kHz. The plasma technology would also be useful for relocating conventional fossil fuel dependent acetylene production to the sun-belt where solar thermal power, which is relatively inexpensive among renewable energies, can be utilized to generate plasma. Such relocation accompanied by replacement of fossil energy with renewable energy would result in reduction of global CO2 emission.