Journal of Chemical Physics, Vol.118, No.19, 8882-8890, 2003
Mathematical model of reaction rate oscillations on a chain of nm-sized catalyst particles
The model of reaction rate oscillations over the surface of nanoparticles embedded into zeolite matrix is numerically investigated. The reaction rate oscillations on each particle are described by a lumped model. The reactions on separate particles interact via the gas diffusion through the pores, which is modeled in the frame of the Maxwell-Stefan approach. The reaction reveals a complex dynamical behavior if a nonhomogeneous distribution of reagent concentrations exists along the chain of particles with a sufficiently large gradient near the ends of the chain. (C) 2003 American Institute of Physics.