화학공학소재연구정보센터
Journal of Colloid and Interface Science, Vol.260, No.2, 339-343, 2003
Electrostatic interaction between ion-penetrable membranes in a salt-free medium
A set of coupled equations is given which determines the distributions of the electric potential and counterions in a system of two interacting identical ion-penetrable membranes of thickness d at separation h immersed in a salt-free medium containing only counterions. The solution to these coupled equations also gives the electrostatic repulsive force between the membranes. It is shown that the interaction force remains finite at h --> 0, unlike the case of the interaction between two planar charged surfaces (d --> 0), and that the interaction force becomes independent of the membrane fixed charge and membrane thickness d at very large h. Finally, an approximate single transcendental equation giving the solution to the coupled equations is derived. (C) 2003 Elsevier Science (USA). All rights reserved.