Through-chip electrodes with high aspect ratios can offer the shortest interconnection and reduce signal delay. Copper has been selected as that electrode material because of its good compatibility to conventional multilayer interconnection in large-scale integration and back end-of-line processes. In this paper, filling vias with higher aspect ratio, 10 mum(2) and 70 mum depth, used for through-chip electrodes is reported. Removing overhang at via tops is important to achieve perfect via filling. Upon testing a series of electrodeposition conditions, conformal electrodeposits were obtained. With those conformal electrodeposits, seams and voids always remained at the via center. Perfect via filling was achieved by the pulse reverse plating method and by increasing Janus Green B concentration up to 20 mg/L in the plating bath. (C) 2003 The Electrochemical Society.