화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Polymer(Korea), Vol.27, No.4, 392-395, July, 2003
Export Citation
에폭시-점토 나노복합체의 제조 및 성질
Synthesis and Properties of Epoxy-Clay Nanocomposites
이충로, 인교진1, 공명선1, †
  • 단국대학교 화학과, 충남 330-714
  • 1강원대학교 화학공학과, 강원 200-701
Chung Ro Lee, Kyo Jin Ihn1, and Myoung Seon Gong1, †
  • Department of Chemistry, Dankook University, San #29, Anseo-dong, Cheonan-si, Chungnam 330-714, Korea
  • 1Department of Chemical Engineering, Kangwon National University, 192-1, Hyoja2-dong, Chunchon, Kangwon 200-701, Korea
E-mail:
초록
포스포늄 염으로 교환된 몬모릴로나이트를 alkyl triphenyl phosponium bromide과 Na+-몬모릴로나이트로부터 제조하였다. 에폭시-점토 나노복합체는 cycloaliphtic epoxy, 산무수물 경화제 그리고 triphenyl butyl phosphonium bromide를 촉진제로 사용하여 제조하였다. TEM과 XRD자료로부터 점토가 에폭시-몬모릴로나이트 복합체 속에 층간삽입되었음을 확인하였다. 그 밖에 기계적 성질로서 인장율과 인장 강도를 측정하였으며 그 특성을 평가하였다.
Phosphonium salt exchanged montmorillonites were prepared from a reaction between alkyl triphenyl phosponium bromide and Na+-montmorillonite. Epoxy-clay nanocomposites were also prepared by using cycloaliphtic epoxy, methyl tetrahydrophthalic anhydride as a hardener, and triphenyl butyl phosphonium bromide as an accelerator. TEM and XRD results suggested that clay minerals in the epoxy-montmorillonites composite were intercalated. Mechanical properties such as tensile modulus and strength were measured and the effect of nanocomposite formation was also discussed.
Keywords:Na+-montmorillonite;nanocomposite;clay;intercalation;phosphonium salts;epoxy
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