화학공학소재연구정보센터
HWAHAK KONGHAK, Vol.41, No.4, 415-425, August, 2003
대기중 이산화탄소 배출 제어를 위한 분리막 기술
Membrane Separation for CO2 Emission Control
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초록
온실효과에 의한 지구 온난화 현상의 주요 원인이 되는 이산화탄소의 대기중 배출 제어를 위한 대책 기술의 하나로서 에너지 저 소비형 분리막 기술이 최근 주목을 받고 있다. 본 논문에서는 이산화탄소를 효율적으로 분리하기 위한 각종 분리막의 개념을 소개하고, 지금까지 개발된 이산화탄소 분리용 고분자막, 무기막, 중공사 접촉기막을 중심으로 국내의 연구 개발 동향과 향후 연구 전망에 대해서 해설하였다.
Membrane separation technology is attracting much attention as an efficient tool for carbon dioxide reduction to migrate the green house effects. In this paper, we introduce concepts of membranes for carbon dioxide separation and review many researches relating to polymeric membranes, inorganic membranes and hollow fiber membrane contactor.
  1. Ihm N, Survey Report on New Technology Trends for Greenhouse Gas Reduction, Korean Intellectual Properties Office (KIPO), Seoul (2001)
  2. http://co2.kemco.or.kr/ (2000)
  3. Noble RD, Stern SA, Membrane Separations Technology, Elsevier, Netherlands, 683-684 (1995)
  4. Uhlhorn RJR, Keizer K, Burggraaf AJ, J. Membr. Sci., 66, 271 (1992) 
  5. Kesting RE, Fritzsche AK, Polymeric Gas Separation Membranes, John Wiley & Sons, Inc., New York, 19-20 (1993)
  6. Brinker CJ, Ward TL, Sehgal R, Raman NK, Hietala DM, Smith DW, Hua D, Headleg TJ, J. Membr. Sci., 77, 165 (1993) 
  7. Brinker CJ, Sehgal R, Hietala SL, Deshpande R, Smith DM, Loy D, Ashley CS, J. Membr. Sci., 94, 85 (1994)
  8. Raman NK, Brinker CJ, J. Membr. Sci., 105(3), 273 (1995) 
  9. Tsai CY, Tam SY, Lu YF, Brinker CJ, J. Membr. Sci., 169(2), 255 (2000) 
  10. Kusakabe K, Kuroda T, Murata A, Morooka S, Ind. Eng. Chem. Res., 36(3), 649 (1997) 
  11. Xiao J, Chem. Eng. Sci., 47, 1123 (1992) 
  12. Kapteijn F, Bakker WJW, Zheng G, Poppe J, Moulijn JA, Chem. Eng. J., 57, 145 (1995)
  13. Bakker WJ, Kapteijn F, Poppe J, Moulijn JA, J. Membr. Sci., 117(1-2), 57 (1996) 
  14. Uhlhorn RJR, Keizer K, Burggraaf AJ, J. Membr. Sci., 66, 259 (1992) 
  15. Cho YK, Han KW, Lee KH, J. Membr. Sci., 104(3), 219 (1995) 
  16. Hyun SH, Jo SY, Kang BS, J. Membr. Sci., 120(2), 197 (1996) 
  17. Japan Fine Ceramics Center: Report on Carbon Dioxide Recovery and Utilizing Technology (1997)
  18. Sea BK, Kusakabe K, Morooka S, J. Membr. Sci., 130(1-2), 41 (1997) 
  19. Kim SS, Choi HC, Park TO, Kim TK, Sea B, J. Korean Environ. Sci. Soc., 9, 311 (2000)
  20. Kim SS, Sea BK, Lee YB, Park HC, Kim TO, Korean J. Mater. Res., 11(7), 622 (2001)
  21. Okui T, Saito Y, Okubo T, Sadakata M, J. Sol-Gel Sci. Tech., 5, 127 (1995) 
  22. Hayashi J, Yamamoto M, Kusakabe K, Morooka S, Ind. Eng. Chem. Res., 36(6), 2134 (1997) 
  23. Kawakami H, Mikawa M, Nagaoka S, J. Membr. Sci., 137(1-2), 241 (1997) 
  24. Maier G, Wolf M, Bleha M, Pientka Z, J. Membr. Sci., 143(1-2), 115 (1998) 
  25. Suzuki H, Tanaka K, Kita H, Okamoto K, Hoshino H, Yoshinaga T, Kusuki Y, J. Membr. Sci., 146(1), 31 (1998) 
  26. Stern SA, Mi Y, Yamamoto H, J. Polym. Sci. B: Polym. Phys., 27, 1887 (1989) 
  27. Coleman MR, J. Membr. Sci., 50, 285 (1993) 
  28. Li JT, Wang SC, Nagai K, Nakagawa T, Mau AWH, J. Membr. Sci., 138(2), 143 (1998) 
  29. Ismail AF, Shilton SJ, J. Membr. Sci., 139(2), 285 (1998) 
  30. Shah VM, Hardy BJ, Stern SA, J. Polym. Sci. B: Polym. Phys., 31, 313 (1993) 
  31. Erb AJ, Paul DR, J. Membr. Sci., 8, 11 (1981) 
  32. Chiou JS, Paul DR, J. Appl. Polym. Sci., 33, 2935 (1987) 
  33. Hellums MW, Koros WJ, Schmidhauser JC, J. Membr. Sci., 67, 75 (1992) 
  34. McHattie JS, Koros WJ, Paul DR, Polymer, 32, 2618 (1991) 
  35. Aitken CL, Koros WJ, Paul DR, Macromolecules, 25, 3651 (1992) 
  36. Aitken CL, Paul DR, J. Polym. Sci. B: Polym. Phys., 31, 983 (1993) 
  37. Hirayama Y, Kase Y, Tanihara R, Sumiyama Y, Kusuki Y, Haraya K, J. Membr. Sci., 160(1), 87 (1999) 
  38. Hirayama Y, Kazama S, Kamizawa C, Energy Conv. Manag., 36, 435 (1995) 
  39. Haraya K, Membrane, 20, 10 (1995)
  40. Suzuki H, Tanaka K, Kita H, Okamoto K, Hoshino H, Yoshinaga T, Kusuki Y, J. Membr. Sci., 146(1), 31 (1998) 
  41. Matsuyama H, Teramoto M, Sakakura H, Iwai K, J. Membr. Sci., 117(1-2), 251 (1996) 
  42. Zhang WZ, Nodera M, Satoh A, Komiyama J, Membrane, 35, 311 (1998)
  43. Nakabayashi M, Okabe E, Fujisawa Y, Hirayama S, Kazama N, Matsumiya K, Takagi H, Mano K, Haraya K, Kamizawa C, Energy Conv. Manag., 36, 419 (1995) 
  44. Hendriks C, Carbon Dioxide Removal from Coal-Fired Power Plants, Kluwer Academic Publichers, Netherlands, 63-64 (1994)
  45. Kreulen H, Smolders CA, Versteeg GF, vanSwaaij WPM, J. Membr. Sci., 78, 197 (1993) 
  46. Yang MC, Cussler EL, AIChE J., 32, 1910 (1986) 
  47. Rangwala HA, J. Membr. Sci., 112(2), 229 (1996) 
  48. Gabelman A, Hwang ST, J. Membr. Sci., 159(1-2), 61 (1999) 
  49. Teramoto M, Matsuyama H, Yamashiro T, Okamoto S, J. Membr. Sci., 45, 115 (1989) 
  50. Shelekhim AB, Beckman IN, J. Membr. Sci., 73, 73 (1992) 
  51. Nishikawa N, Ishibashi M, Ohta H, Akutsu N, Matsumoto H, Kamata T, Kitamira H, Energy Conv. Manag., 36, 415 (1995) 
  52. Li K, Teo WK, Sep. Purif. Technol., 13, 79 (1998) 
  53. Lee KH, Membr. J., 4, 78 (1994)
  54. Kim JH, Rhim JW, Lee SB, Membr. J., 12, 121 (2002)
  55. Kang PH, Lee KH, Yang HS, J. Korean Ind. Eng. Chem., 10(8), 1099 (1999)
  56. Sea B, Lee KH, Bull. Korean Chem. Soc., 22, 1400 (2001)
  57. Park YI, Lee KH, J. Ind. Eng. Chem., 5(3), 235 (1999)
  58. Park YI, Lee KH, J. Appl. Polym. Sci., 80(10), 1785 (2001) 
  59. Jurn DG, Park YI, Lee KH, J. Korean Ind. Eng. Chem., 11(1), 34 (2000)
  60. Kim MJ, Park YI, Sea B, Youm KH, Lee KH, J. Appl. Polym. Sci., in press (2003)
  61. Chun MS, Lee KH, Sep. Sci. Technol., 32(15), 2445 (1997)
  62. Cho IK, Lee YT, Park YI, Lee KH, Membr. J., 10, 39 (2000)
  63. Lee Y, Park YI, Jurn D, Lee Y, Lee KH, HWAHAK KONGHAK, 38(1), 32 (2000)
  64. Yeon SH, Sea B, Park YI, Lee KH, HWAHAK KONGHAK, 39(6), 709 (2001)
  65. Kang MS, Moon SH, Park YI, Lee KH, Sep. Sci. Technol., 37(8), 1789 (2002) 
  66. Lee YT, Noble RD, Yeom BY, Park YI, Lee KH, J. Membr. Sci., 194(1), 57 (2001) 
  67. Yeon SH, Sea B, Park YI, Lee KH, Sep. Sci. Technol., 38(2), 271 (2003) 
  68. Park SB, Shim CS, Lee H, Lee KH, Fluid Phase Equilib., 134(1-2), 141 (1997) 
  69. Yeon SH, Sea B, Lee KS, Park YI, Lee KH, J. Korean Ind. Eng. Chem., 13(8), 787 (2002)
  70. Kim JH, Ha SY, Lee YM, J. Membr. Sci., 190(2), 179 (2001) 
  71. Yong HH, Park NC, Kang YS, Won J, Kim WN, J. Membr. Sci., 188(2), 151 (2001) 
  72. Kim YS, Yang SM, Sep. Purif. Technol., 21, 101 (2000) 
  73. Hahm MK, Sohn WI, Lee YT, Kim IH, Lee SB, Membr. J., 10, 130 (2000)
  74. Ahn JS, Lee SM, HWAHAK KONGHAK, 34(6), 675 (1996)
  75. Woo K, Hwang JD, Jeong SY, Jang GH, Clean Technol., 7(1), 43 (2001)
  76. Takeuchi M, Matsumiya N, Niwa S, Greenhouse Gas Control Technology; Study on CO2 Global Recycling System, Elsevier Science Ltd., Netherlands, 433-438 (1999)