Journal of Chemical Physics, Vol.119, No.4, 2338-2347, 2003
A simple harmonic model as a caricature for mismatch and relaxation effects for ion hopping dynamics in solid electrolytes
We formulate a simple harmonic mean-field model with N+1 particles and analyze the relaxation processes following a jump of one of these particles. Either the particle can jump back (single-particle route) or the other N particles adjust themselves (multiparticle route). The dynamics of this model is solved analytically in the linear response regime. Furthermore, we relate these results to a phenomenological approach by Funke and co-workers (concept of mismatch and relaxation, CMR) which has been successfully used to model conductivity spectra in the field of ion dynamics in solid electrolytes. Since the mean-field model contains the relevant ingredients of the CMR-approach, a comparison of the resulting rate equations with the CMR-equations becomes possible. Generalizations beyond the mean-field case are discussed. (C) 2003 American Institute of Physics.