화학공학소재연구정보센터
Journal of Physical Chemistry B, Vol.107, No.24, 5667-5669, 2003
Near-infrared absorbance of single-walled carbon nanotubes dispersed in dimethylformamide
Absorption spectra of single-walled carbon nanotubes (SWNT) dispersed in dimethylformamide (DMF) have been recorded in the visible to near-infrared range. Besides broad absorption bands, the spectra show a sharp peak at 5187 cm(-1), which has been attributed in the literature to the absorption of semiconducting nanotubes with a band gap of 0.64 eV [Ausman et al. J. Phys. Chem. B 2000, 104, 8911]. On the basis of absorbance measurements for samples that show the sharp absorbance peak but do not contain SWNTs, we conclude that the origin of the peak at 5187 cm(-1) is not due to semiconducting nanotubes but due to water present in the SWNT/DMF suspension. A comparative study of D2O in DMF reproduces a similar peak that is isotope-shifted into the near-infrared.