We report accurate geometries and harmonic force fields for trans- and cis-azobenzene determined by second-order Mphiller-Plesset perturbation theory. For the trans isomer, the planar structure with C-2h symmetry, found in a recent gas electron diffraction experiment, is verified. The calculated vibrational spectra are compared with experimental data and density functional calculations. Important vibrational frequencies are localized and discussed. For both isomers, we report UV spectra calculated using the second-order approximate coupled-cluster singles-and-doubles model CC2 with accurate basis sets. Vertical excitation energies and oscillator strengths have been determined for the lowest singlet npi* and pipi* transitions. The results are compared with the available experimental data and second-order polarization propagator (SOPPA) and density functional (DFT) calculations. For both isomers, the CC2 results for the excitation energies into the S-1 and S-2 states agree within 0.1 eV with experimental gas-phase measurements.