화학공학소재연구정보센터
Applied Chemistry, Vol.7, No.2, 503-506, October, 2003
고온 리튬용융염계에서 오스테나이트 스테인레스강의 부식거동
Corrosion Behavior of Austenitic Stainless Steels in the Hot Lithium Molten Salts
In the development of the advanced spent fuel management process based on the molten salt technology, it is essential to choose the optimum material for the process equipment handling molten salt. As a part of assessment and application of the structural material for the molten salt handling system, corrosion behavior of 304, 304L and 316LN in the molten salts was investigated. Corrosion proceeded via three steps; the formation step of corrosion product in which rapid corrosion takes place until stable corrosion product is formed after the beginning of corrosion, the protection step against corrosion until breakaway occurs after the formation step of stable corrosion product and the advancing step of corrosion after the breakaway. In a molten salt of LiCl-8%Li2O, the final oxide scales of Li2Ni8O10 were formed, and also Li2Ni8O10 in the molten salt of LiCl-8%Li2O-1%Li3N.