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Journal of Physical Chemistry A, Vol.107, No.39, 7667-7670, 2003
The kinetic isotope effects in the reactions of four ethene isotopologues with chlorine and bromine atoms
The kinetic isotope effects (KIEs) have been studied in the reactions of chlorine and bromine atoms with four ethene isotopologues (C2H4, (C2H4)-C-13, C2D4, and C2H3D) using FTIR spectroscopy and the relative rate technique. Halogen atoms were produced by the photolysis of Cl-2 and Br-2. For chlorine the KIEs, defined as k(C2)H(4)/k(x), were: 0.738 +/- 0.024 (C2D4), 0.853 +/- 0.037 (C2H3D), and 1.061 +/- 0.023 ((C2H4)-C-13) and for bromine: 0.817 +/- 0.016 (C2D4), 1.09 +/- 0.13 (C2H3D), and 1.1172 +/- 0.0053 ((C2H4)-C-13). Uncertainties are given as 2sigma. These results are interpreted in terms of the fate of the atom-molecule adduct. The implications of the results to atmospheric chemistry are described.