Journal of Physical Chemistry A, Vol.107, No.40, 8177-8183, 2003
Stern-Volmer law in competing theories and approximations
The numerous theories of contact energy quenching are compared between themselves and with the theories of remote electron transfer. The Stern-Volmer constant used as a criterion is studied in the full range of quencher concentrations and diffusion. When any one of these parameters is increased, diffusion-controlled quenching gives way to kinetic control, although differently in the theories of contact and remote transfer.