Journal of Applied Polymer Science, Vol.91, No.3, 1505-1513, 2004
Effects of convergent flow on in situ fibrillation of TLCP in PEN
A polymer melt entering a capillary die from a cylinder undergoes a convergent flow in which there is a complex combination of extensional and shear flows. The convergent flow plays an important role in controlling the in situ fibrillation of thermotropic liquid crystalline polymer (TLCP) in a thermoplastic matrix melt. This study examines effects of the convergent flow on development of TLCP fibrils in a TLCP/poly(ethylene naphthalate) (PEN) blend. A capillary rheometer was used and the extent of the convergent flow was varied by changing capillary dimension and shear rate. With a given capillary die, the TLCP fibrillation was found to increase with increasing shear rate because of the increased deformation of TLCP droplets. The establishment of a fully developed shear velocity profile by using a relatively long die is considered to be necessary to retain the TLCP fibrils initiated in the convergent flow region. At a given high shear rate, TLCP fibrillation improves with increasing capillary diameter (:52 mm) because of the increased difference in velocity between the capillary and the cylinder. (C) 2003 Wiley Periodicals, Inc. J AppI Polym Sci 91: 1505-1513,2004.