Journal of Physical Chemistry A, Vol.107, No.50, 11008-11012, 2003
Meandering spiral waves in the 1,4-cyclohexanedione Belousov-Zhabotinsky system catalyzed by Fe[batho(SO3)(2)](3)(4-/3-)
Meandering spiral waves are observed in the 1,4-cyclohexanedione Belousov-Zhabotinsky (CHD-BZ) reaction at very low concentrations (3-35 mM) of the organic substrate. The spiral tips describe hypocycle-like trajectories indicating the presence of two main rotation periods and radii. The ratio of these periods approaches I for decreasing concentrations of CHD. In this limit, we find Z-shaped trajectories with approximately two lobes. The use of Fe[batho(SO3)(2)](3)(4-/3-) as the BZ catalyst gives rise to extremely long rotation periods (1000-4000 s), and the tip trajectories span large areas of up to 40 mm(2). As a result of the absence of gaseous products and the high absorption of the catalyst, this particular system is ideally suited for the investigation of spiral waves in closed, thin-layer systems, such as nonuniformly curved and micropatterned media.