화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.10, No.1, 1-15, January, 2004
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Recent advances in solid superacids
Jong Rack Sohn†
  • Department of Industrial Chemistry, Engineering College, Kyungpook National University, Daeju 70-701, Korea
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Recent advances in solid superacids are reviewed. The acid stronger than H-0 = -11.93, which corresponds to the acid strength of 100% H2SO4, is known as superacid. Solid superacid catalysts have many advantages such as an easy separation of products from catalyst, the repeated use and regeneration of catalysts, as compared with liquid superacids. The preparation methods, surface properties including acid amount and acid strength, structures of acid sites, and the applications of solid superacid catalysts for several chemical reactions are presented.
Keywords:solid superacid catalyst;preparation method;structure of acid sites;applications of catalysts
  1. Tanabe K, Misono M, Ono Y, Hattori H, New Solide Acids and Bases, Kodansa, Tokyo (1989)
  2. Yamaguchi T, Appl. Catal., 61, 1 (1990) 
  3. Arata K, Adv. Catal., 37, 165 (1990)
  4. Gillespie RJ, Peel TE, Adv. Phys. Org. Chem., 9, 1 (1972)
  5. Hammett LP, Deyrup AJ, J. Am. Chem. Soc., 54, 2721 (1932)
  6. Brand JCD, Horning WC, Thornley MB, J. Chem. Soc., 1374 (1952)
  7. Gillespie RJ, Peel TE, Robinson EA, J. Am. Chem. Soc., 93, 5083 (1971)
  8. Gillespie RJ, Peel TE, J. Am. Chem. Soc., 95, 5173 (1973)
  9. Olah GA, Prakash GKS, Sommer J, Superacids, John Wiley & Sons, New York (1985)
  10. Kemp JD, U.S. Patent, 3,979,476 (1976)
  11. Bloch HS, Br. Patent, 1,389,237 (1972)
  12. Rodewald PG, Whitehurst DD, U.S. Patent, 3,925,251 (1975)
  13. Oelderik JM, U.S. Patent, 3,394,202 (1968)
  14. Oelderik JM, Mackor EL, Plattecuw JC, vanderWiel A, U.S. Patent, 3,201,494 (1965)
  15. Oelderik JM, Can. Patent, 794,400 (1968)
  16. Bloch HS, U.S. Patent, 3,678,120 (1972)
  17. Olah GA, U.S. Patent, 3,766,286 (1973)
  18. Gardner LE, U.S. Patent, 3,878,261 (1975)
  19. McCaulay DA, U.S. Patent, 4,035,286 (1977)
  20. Rodewald PG, U.S. Patent, 3,984,352 (1976)
  21. Takahashi O, Yamauchi T, Sakuhara T, Hattori H, Tanabe K, Bull. Chem. Soc. Jpn., 53, 1807 (1980)
  22. Hattori H, Takahashi O, Takagi M, Tanabe K, J. Catal., 68, 132 (1981)
  23. Takahashi O, Hattori H, J. Catal., 68, 144 (1981)
  24. Kelly JT, Sechrist CN, U.S. Patent, 3,248,343 (1966)
  25. Olah GA, Messina G, U.S. Patent, 3,993,587 (1976)
  26. Hammer GP, Mattox WJ, U.S. Patent, 3,961,036 (1976)
  27. Herbstman S, Webb AN, Estes JH, U.S. Patent, 4,066,716 (1978)
  28. Drago RS, Getty EE, U.S. Patent, 4,719,190 (1988)
  29. Getty EE, Drago RS, Inorg. Chem., 29, 1186 (1990)
  30. Hino M, Arata K, J. Chem. Soc.-Chem. Commun., 851 (1980)
  31. Hino M, Kobayashi S, Arata K, J. Am. Chem. Soc., 101, 6439 (1979)
  32. Jin T, Yamaguchi T, Tanabe K, J. Phys. Chem., 90, 4794 (1986)
  33. Sohn JR, Jang HJ, Park MY, Park EH, Park SE, J. Mol. Catal., 93, 149 (1994) 
  34. Sohn JR, Jang HJ, J. Mol. Catal., 64, 360 (1991)
  35. Kayo A, Yamaguchi T, Tanabe K, J. Catal., 83, 99 (1983)
  36. Yamaguchi T, Jin T, Tanabe K, J. Phys. Chem., 90, 3148 (1986)
  37. Sohn JR, Kim HW, J. Mol. Catal., 52, 361 (1989) 
  38. Tanabe K, Ishiya C, Matsuzaki I, Ichikawa I, Hattori H, Bull. Chem. Soc. Jpn., 45, 47 (1972)
  39. Nakano Y, Iizuka T, Hattori H, Tanabe K, J. Catal., 57, 1 (1979)
  40. Tanabe K, Hattori H, Yamaguchi T, Critical Rev. Surf. Chem., 1, 1 (1990)
  41. Hino M, Arata K, Chem. Lett., 963 (1980)
  42. Tanabe K, Hattori H, Ban'i Y, Mitsutani A, Japan Patent, 55-115570 (1980)
  43. Chen Z, Iiuka T, Tanabe K, Chem. Lett., 1085 (1984)
  44. Hino M, Arata K, Chem. Lett., 1671 (1981)
  45. Sohn JR, Kim HW, Park MY, Park EH, Kim JT, Park SE, Appl. Catal. A: Gen., 128(1), 127 (1995)
  46. Sohn JR, Kim HJ, J. Catal., 101, 428 (1986)
  47. Jin T, Machida M, Yamaguchi T, Tanabe K, Inorg. Chem., 23, 4396 (1984)
  48. Hino M, Arata K, Yabe K, Shokubai, 22, 232 (1980)
  49. Arata K, Hino M, Hyomen, 19, 75 (1981)
  50. Saur O, Bensitel M, Mohammed Saad AB, Lavalley JC, Tripp CP, Morrow BA, J. Catal., 99, 104 (1986)
  51. Datta A, Cavell G, J. Phys. Chem., 89, 443 (1985)
  52. Holstein EJ, Wei JT, Hsu CY, U.S. Patent, 4,918,041 (1990)
  53. Hsu CY, Patel VK, Vahising DH, Wei JT, Myers HK, U.S. Patent, 5,091,671 (1991)
  54. Lange FC, Cheung TK, Gates BC, Catal. Lett., 41(1-2), 95 (1996)
  55. Jatia A, Chang C, Macleod JD, Okubo T, Davis ME, Catal. Lett., 25(1-2), 21 (1994)
  56. Davis BH, Keogh RA, Srinivasan R, Catal. Today, 20, 219 (1994)
  57. Lin CH, Hsu CY, J. Chem. Soc.-Chem. Commun., 1479 (1992)
  58. Olah GA, Schlossberg RH, J. Am. Chem. Soc., 90, 2726 (1968)
  59. Scurrell MS, Appl. Catal., 34, 109 (1987) 
  60. Zarkalis AS, Hsu CY, Gates BC, Catal. Lett., 29(1-2), 235 (1994)
  61. Cheung TK, Gates BC, J. Catal., 168(2), 522 (1997)
  62. Cheung TK, Gates BC, Chem. Commun., 1937 (1996)
  63. Hosoi T, Shimidzu T, Itoh S, Baba S, Takaoka H, Imai T, Yokoyama N, Am. Chem. Soc. Div. Petr. Chem. Prepr., 33, 562 (1988)
  64. Ebitani K, Konishi J, Hattori H, J. Catal., 130, 257 (1991)
  65. Ebitani K, Tsuji J, Hattori H, Kita H, J. Catal., 135, 609 (1992)
  66. Song XM, Reddy KR, Sayari A, J. Catal., 161(1), 206 (1996)
  67. Baba S, Shibata Y, Takaoka H, Kimura T, Tkasaka K, Japan Patent, 61 (1986)
  68. Ebitani K, Konishi J, Horie A, Hattori A, Tanabe K, Acid-Base Catalysts, Kodansa, Tokyo (1989)
  69. Tanabe K, Misono M, Ono Y, Httori H, New Solid Acids and Bases, Elsevier Science, Amsterdam (1989)
  70. Arata K, Hino M, Yamagata M, Bull. Chem. Soc. Jpn., 63, 244 (1990)
  71. Sohn JR, Park EH, J. Ind. Eng. Chem., 4(3), 197 (1998)
  72. Sohn JR, Kim JG, Kwon TD, Park EH, Langmuir, 18(5), 1666 (2002)
  73. Sohn JR, Kwon TD, Kim SB, Bull. Korean Chem. Soc., 22, 1309 (2001)
  74. Sohn JR, Kwon TD, Kim SB, J. Ind. Eng. Chem., 7(6), 441 (2001)
  75. Sohn JR, Park WC, Park SE, Catal. Lett., 81(3-4), 259 (2002)
  76. Sohn JR, Park WC, Korean J. Chem. Eng., 19(4), 580 (2002)
  77. Sohn JR, Park WC, Kim HW, J. Catal., 209(1), 69 (2002)
  78. Sohn JR, Park WC, Appl. Catal. A: Gen., 239(1-2), 269 (2003)
  79. Sohn JR, Park EH, J. Ind. Eng. Chem., 6(5), 312 (2000)
  80. Sohn JR, Lee SY, Appl. Catal. A: Gen., 164(1-2), 127 (1997)
  81. Sohn JR, Park EH, Kim HW, J. Ind. Eng. Chem., 5(4), 253 (1999)
  82. Sohn JR, Cho SG, Pae YI, Hayashi S, J. Catal., 159(1), 170 (1996)
  83. Sohn JR, Park MY, J. Ind. Eng. Chem., 4(2), 84 (1998)
  84. Sohn JR, Park WC, Appl. Catal. A: Gen., 230(1-2), 11 (2002)
  85. Sohn JR, Park WC, Bull. Korean Chem. Soc., 22, 1303 (2001)
  86. Sohn JR, Ozaki A, J. Catal., 61, 291 (1980)
  87. Sohn JR, Shin DC, J. Catal., 160(2), 314 (1996)
  88. Sohn JR, Park WC, Bull. Korean Chem. Soc., 21, 1063 (2000)
  89. Hua WM, Xia YD, Yue YH, Gao Z, J. Catal., 196(1), 104 (2000)
  90. Sohn JR, Park MY, Langmuir, 14(21), 6140 (1998)
  91. Hino M, Arata K, J. Chem. Soc.-Chem. Commun., 1259 (1988)
  92. Hino M, Arata K, Chem. Lett., 971 (1989)
  93. Sohn JR, Lee SY, Appl. Catal. A: Gen., 164(1-2), 127 (1997)
  94. Hino M, Arata K, J. Chem. Soc.-Chem. Commun. (1987)
  95. Gutierrez-Alejandre A, Ramirez J, Busca G, Langmuir, 14(3), 630 (1998)
  96. Barton DG, Soled SL, Meitzner GD, Fuentes GA, Iglesia E, J. Catal., 181(1), 57 (1999)
  97. Sohn JR, Kim JG, Kwon TD, Park EH, Langmuir, 18(5), 1666 (2002)
  98. Scheithauer M, Grasselli RK, Knozinger H, Langmuir, 14(11), 3019 (1998)
  99. Arata K, Hino M, Shokubai, 31, 477 (1989)
  100. Wang SB, Murata K, Hayakawa T, Hamakawa S, Suzuki K, Appl. Catal. A: Gen., 196(1), 1 (2000)
  101. Myers DL, Lunsford JH, J. Catal., 99, 140 (1986)
  102. Flick DW, Huff MC, Appl. Catal. A: Gen., 187(1), 13 (1999)
  103. Feijen-Jeurissen MMR, Jorna JJ, Nieuwenhuys BE, Sinquin G, Petit C, Hindermann JP, Catal. Today, 54(1), 65 (1999)
  104. Kohler K, Engweiler J, Viebrock H, Baiker A, Langmuir, 11(9), 3423 (1995)
  105. Weckhuysen BM, Wachs IE, Schoonheydt RA, Chem. Rev., 96(8), 3327 (1996)
  106. Hino M, Arata K, J. Chem. Soc.-Chem. Commun., 1355 (1987)
  107. Sohn JR, Ryu SG, Langmuir, 9, 126 (1993)
  108. Sohn JR, Ryu SG, Kim HW, J. Mol. Catal. A-Chem., 135, 99 (1998)
  109. Sohn JR, Ryu SG, Catal. Lett., 74(1-2), 105 (2001)
  110. Wash IE, Deo G, Kim DS, Vuurman MA, Hu H, Proc. 10th Int. Congr., L. Guczi, F. Solymosi, and P. Ttny (eds.), Budpast (1992)
  111. Hucknall DJ, Selective Oxidation of Hydrocarbons, Academic Press, London (1997)
  112. Martin C, Martin I, River V, J. Chem. Soc.-Faraday Trans., 89, 4131 (1993)
  113. Ono T, Anpo M, Kubokawa Y, J. Phys. Chem., 90, 4780 (1986)
  114. Princ R, deBeer VHJ, Somorjai GA, Catal. Rev.-Sci. Eng., 31, 1 (1989)
  115. Ratnasamy P, Sivasanker S, Catal. Rev.-Sci. Eng., 22, 401 (1980)
  116. Massoth FE, Adv. Catal., 27, 265 (1978)
  117. Pratt KC, Sanders JV, Christov V, J. Catal., 124, 416 (1990)
  118. Hamon D, Vrinat M, Breysse M, Durand B, Jebrouni M, Roubin M, Magnoux P, DesCourires T, Catal. Today, 10, 613 (1991)
  119. Duchet JC, Tilliette MJ, Cornet D, Vivier L, Perot G, Bekakra L, Moreau C, Szabo G, Catal. Today, 10, 579 (1991)
  120. Portefaix JL, Cattenot M, Dalmon JA, Mauchauss C, Advances in Hydrotreating Catalysis, M.L. Occelli and R.G. Anthony (eds.), Elsevier, Amsterdam, 243 (1989)
  121. Afanasiev P, Geantet C, Breysse M, J. Catal., 153(1), 17 (1995)
  122. Zhao B, Wang X, Ma H, Tong Y, J. Mol. Catal. A-Chem., 108, 167 (1996)
  123. Brown ASC, Hargreaves JSJ, Taylor SH, Catal. Lett., 57(3), 109 (1999)