화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.10, No.1, 161-171, January, 2004
Chemistry of ferrate (Fe(VI)) in aqueous solution and its applications as a green chemical
E-mail:
In recent years considerable attention has been paid to ferrate (Fe(VI)), +6 oxidation state of iron due to its novel properties such as oxidizing power, selective reactivity, stability as salt, and non-toxic by-products of ferric ion. Especially, much progress has been made on its applications to water treatments as efficient oxidant, coagulant and disinfectant. Reflecting the increasing interests on applications of Fe(VI) as a green chemical, this paper reviewed extensively not only the chemistry of Fe(VI) but also its various applications with focusing on its water treatment applications. The required future works for its widespread and successful applications to various fields were also discussed in the relevant parts.
  1. Thompson GW, Ockerman LT, Schreyer JM, J. Am. Chem. Soc., 73, 1379 (1951)
  2. Audette RJ, Quail JW, Inorg. Chem., 11, 1904 (1972)
  3. Bielski BHJ, Free Rad. Res. Comms., 12, 469 (1991)
  4. Waite TD, Gray KA, Stud. Environ. Sci., 407 (1984)
  5. Carr JD, Kelter PB, Tabatabai A, Spichal D, Erickson J, McLaughin CW, Proc. Conf. Water Chlorin. Chem. Environ. Impact Health Effects, R.L. Jolley Eds., pp. 1285-1298, New York (1985)
  6. Sharma VK, Adv. Environ. Res., 6, 143 (2002)
  7. Jiang JQ, Lloyd B, Water Res., 36, 1397 (2002)
  8. Licht S, Wang B, Ghosh S, Science, 28, 1039 (1999)
  9. Licht S, Naschitz V, Ghosh S, Lin L, Electrochem. Commun., 3, 340 (2001)
  10. Licht S, Ghosh S, J. Power Sources, 109(2), 465 (2002)
  11. Audette RJ, Quail JW, Smith PJ, Tetrahedron Lett., 3, 279 (1971)
  12. Lee DG, Gai AH, Can. J. Chem., 71, 1394 (1993)
  13. Delaude L, Laszlo PA, J. Org. Chem., 61, 6360 (1996)
  14. Bielski BHJ, Annu. Neurol., 32, S28 (1992) 
  15. Sharma VK, Radiat. Phys. Chem., 65, 349 (2002)
  16. Hoppe ML, Schlemper EO, Murmann RK, Acta Crystallogr. Sect. B-Struct. Sci., 38, 2237 (1982)
  17. Goff H, Murmann RK, J. Am. Chem. Soc., 93, 6058 (1971)
  18. Norcross BE, Lewis WC, Gai H, Noureldin NA, Lee DG, Can. J. Chem., 75, 129 (1997)
  19. Wood RH, J. Am. Chem. Soc., 80, 2038 (1958)
  20. Rush JD, Zhao Z, Bielski BHJ, Free Rad. Res., 24, 187 (1996)
  21. Lee YH, Cho M, Yoon J, J. Environ. Hi-tech., 12, 52 (2003)
  22. Ockerman LT, Schreyer JM, J. Am. Chem. Soc., 73, 5478 (1951)
  23. Bailie AG, Bouzek K, Lukasek P, Rousar I, Wragg AA, J. Chem. Technol. Biotechnol., 66(1), 35 (1996)
  24. Veprek-Siska J, Ettel V, Chem. Ind., 1, 548 (1967)
  25. Martinez-Tamayo E, Beltran-Porter A, Beltran-Porter D, Thermochim. Acta, 97, 243 (1986)
  26. Cici M, Cuci Y, Waste Manage., 17, 407 (1997)
  27. Neveux N, Aubertin N, Gerardin R, Evrard O, Chemical Water and Wastewater Treatment III, R. Klute and H.H. Hahn Ed., pp. 95-103, Springer Verlag, BerlinHeidelberg (1994)
  28. Denvir A, Pletcher D, J. Appl. Electrochem., 26(8), 815 (1996)
  29. Denvir A, Pletcher D, J. Appl. Electrochem., 26(8), 823 (1996)
  30. Bouzek K, Rousar I, J. Appl. Electrochem., 26(9), 919 (1996)
  31. Bouzek K, Rousar I, Taylor MA, J. Appl. Electrochem., 26(9), 925 (1996)
  32. Bouzek K, Rousar I, J. Appl. Electrochem., 27(6), 679 (1997)
  33. Bouzek K, Lipovska M, Schmidt M, Rousar I, Wragg AA, Electrochim. Acta, 44(4), 547 (1998)
  34. Bouzek K, Schmidt MJ, Wragg AA, Electrochem. Commun., 1, 370 (1999)
  35. Lapicque F, Valentin G, Electrochem. Commun., 4, 764 (2002)
  36. Licht S, Tel-Vered R, Halperin L, Electrochem. Commun., 4, 933 (2002)
  37. Lee J, Tryk DA, Fujishima A, Park SM, Chem. Commun., 486 (2002)
  38. Murmann RK, Robinson PR, Water Res., 8, 543 (1974)
  39. Waite TD, Gilbert M, J. Water Pollut. Control. Fed., 50, 543 (1978)
  40. Waite TD, ASCE J. Environ. Eng. Div., 105, 1023 (1979)
  41. Carr JD, Kelter PB, Ericson AT, Environ. Sci. Technol., 15, 184 (1981)
  42. DeLuca SJ, Chao AC, Smallwood C, J. Environ. Eng.-ASCE, 109, 36 (1983)
  43. Farooq S, Bari A, J. Environ. Eng.-ASCE, 112, 301 (1983)
  44. Johnson MD, Hornstein BJ, Inorg. Chim. Acta, 225, 145 (1994) 
  45. Johnson MD, Hornstein BJ, Chem. Commun., 965 (1996)
  46. Johnson MD, Read JF, Inorg. Chem., 35(23), 6795 (1996)
  47. Sharma VK, Smith JO, Millero FJ, Environ. Sci. Technol., 31, 2486 (1997)
  48. Sharma VK, Pivera W, Smith JO, O'Brien B, Environ. Sci. Technol., 32, 2608 (1998)
  49. Sharma VK, Bloom JT, Joshi VN, J. Environ. Sci. Health Part A-Toxic/Hazard. Subst. Environ. Eng., 33, 635 (1998)
  50. Read JF, Wyand AEH, Transit. Metal. Chem., 23, 755 (1998) 
  51. Read JF, boucher KD, Mehlman SA, Watson KJ, Inorg. Chim. Acta, 267, 159 (1998) 
  52. Read JF, Adams EK, Gass HJ, Shea SE, Theriault A, Inorg. Chim. Acta, 281, 43 (1998) 
  53. Sharma VK, Rivera W, Joshi VN, Millero FJ, O'Connor D, Environ. Sci. Technol., 33, 2645 (1999)
  54. Read JF, Bewick SA, Graves CR, MacPherson JM, Salah JC, Theriault A, Wyand AEH, Inorg. Chim. Acta, 303, 244 (2000) 
  55. Sharma VK, Rendon RA, Millero FJ, Vazquez FG, Mar. Chem., 70, 235 (2000) 
  56. Read JF, John J, MacPherson J, Schaubel C, Theriault A, Inorg. Chim. Acta, 315, 96 (2001) 
  57. Sharma VK, Burnett CR, O'Conner DB, Cabelli D, Environ. Sci. Technol., 36, 4182 (2002)
  58. Johnson MD, Hornstein BJ, Inorg. Chem., 42(21), 6923 (2003)
  59. Read JF, Graves CR, Jackson E, Inorg. Chim. Acta, 348, 41 (2003) 
  60. Sylvester P, Rutherford LA, Gonzalez-Martin A, Kim J, Rapko BM, Lumetta GJ, Environ. Sci. Technol., 35, 216 (2001)
  61. Murshed M, Rockstraw DA, Hanson AT, Johnson M, Environ. Pollut., 125, 245 (2003)
  62. deLuca SJ, Cantelli M, deLuca MA, Water Sci. Technol., 26, 2077 (1992)
  63. Bartzatt R, Cano M, Johnson L, Nagel D, J. Toxicol. Env. Heal., 35, 205 (1992)
  64. Potts ME, Churchwell DR, Water Environ. Res., 66, 107 (1994)
  65. Midkiff WS, Covey JR, Johnson MD, Water Environ. Res., 67, 1007 (1995)
  66. White DA, Franklin GS, Environ. Technol., 19, 1157 (1998)
  67. Qu JH, Liu HJ, Liu SX, Lei PJ, J. Environ. Eng.-ASCE, 129, 17 (2003)
  68. Ma J, Liu W, Water Res., 36, 871 (2002)
  69. Ma J, Liu W, Water Res., 36, 4959 (2002)
  70. Gillbert MB, Waite TD, Hare C, J. Am. Water Works Assoc., 68, 495 (1976)
  71. Schink T, Waite TD, Water Res., 14, 1705 (1980)
  72. Kazama F, FEMS Microbiol. Lett., 118, 345 (1994)
  73. Kazama F, Water Sci. Technol., 31, 165 (1995)
  74. Waite TD, Fagan J, Condenser Biofouling Control, J. Carvey, Ed., pp. 441-462, Ann Arbor Science, MI (1994)
  75. DeLuca SJ, Idle CN, Chao AC, Water Sci. Technol., 33, 119 (1996)
  76. Stuart L, Wang B, Gosh S, Li J, Naschitz V, Electrochem. Commun., 1, 522 (1999)
  77. Stuart L, Wang B, Xu G, Li J, Naschitz V, Electrochem. Commun., 1, 527 (1999)
  78. Licht S, Naschitz V, Liu B, Ghosh S, Halperin N, Halperin L, Rozen D, J. Power Sources, 99(1-2), 7 (2001)
  79. Licht S, Naschitz V, Halperin L, Halperin N, Lin L, Chen JJ, Ghosh S, Liu B, J. Power Sources, 101(2), 167 (2001)
  80. Licht S, Naschitz V, Wang BH, J. Power Sources, 109(1), 67 (2002)
  81. Audette RJ, Quail JW, Smith PJ, J. Chem. Soc.-Chem. Commun., 38 (1972)
  82. Williams DH, Riley JT, Inorg. Chem. Acta, 8, 177 (1974) 
  83. Tsuda Y, Nakajima S, Chem. Lett., 1397 (1978)
  84. Kim KS, Chang YK, Bae SK, Hahn CS, Synthesis, 866 (1984) 
  85. Firouzabadi H, Mohajer D, Moghadam E, Bull. Chem. Soc. Jpn., 61, 2185 (1988)
  86. Delaude L, Laszlo P, Lehance P, Tetrahedron Lett., 36, 8505 (1995)
  87. Symons MCR, Cutteridge JMC, Free Radicals and Iron: Chemistry, Biology, and Medicine, Oxford Science Publications, New York (1998)
  88. Bielski BHJ, Method Enzymol., 186, 108 (1990)
  89. Rush JD, Bielski BHJ, J. Am. Chem. Soc., 108, 523 (1986)
  90. Bielski BHJ, Thomas MJ, J. Am. Chem. Soc., 109, 7761 (1987)
  91. Rush JD, Bielski BHJ, Inorg. Chem., 28, 3947 (1989)
  92. Sharma VK, Bielski BHJ, Inorg. Chem., 30, 4306 (1991)
  93. Bielski BHJ, Sharma VK, Czapski G, Radiat. Phys. Chem., 44, 479 (1994)
  94. Rush JD, Bielski BH, Inorg. Chem., 33(24), 5499 (1994)
  95. Rush JD, Cyr JE, Zhao Z, Bielski BHJ, Free Rad. Res., 22, 349 (1995)
  96. Rush JD, Bielski BHJ, Free Rad. Res., 22, 571 (1995)
  97. Sharma VK, Burnett CR, Rivera W, Joshi VN, Langmuir, 17(15), 4598 (2001)
  98. Cainelli G, Cardillo G, Chromium Oxidations in Organic Chemistry, Springer-Verlag, Berlin (1984)
  99. Johnson MD, Bernard J, Inorg. Chem., 31, 5140 (1992)
  100. Hornstein BJ, Ph.D. Thesis, New Mexico State University, U.S.A. (1999)
  101. Lee YH, Kim JY, Yoon J, unpublished result
  102. Huang H, Sommerfeld D, Dunn BC, Eyring EM, Lloyd CR, J. Phys. Chem. A, 105(14), 3536 (2001)
  103. Huang H, Sommerfeld D, Dunn B, Christopher R, Lloyd CR, Eyring EM, J. Chem. Soc.-Perkin Trans. 1, 1301 (2001)
  104. Cry JE, Bielski BHJ, Free Rad. Biol. Med., 11, 157 (1991) 
  105. Lee YH, Um IH, Yoon J, Environ. Sci. Technol., 37, 5750 (2003)
  106. Nickson R, McArthur J, Burgess W, Ahmed KM, Ravenscroft P, Rahman M, Nature, 395(6700), 338 (1998)
  107. Hering JG, Chen PY, Wikie JA, Elimelech M, Liang S, J. Am. Water Works Assoc., 88, 155 (1996)
  108. USEPA, Alternative Disinfectants and Oxidants Guidance Manual, USA (1999)
  109. Cho M, Lee YH, Yoon J, Environ. Sci. Technol., Manuscript in Preparation
  110. Cho M, Chung H, Choi S, Yoon J, Proc. Intern. Symp. AWWA Water Quality Technology, Philadephia, U.S.A. (2003)
  111. Langlais B, Reckhow DA, Brink DR, Ozone in Water Treatment: Application and Engineering, Lewis Publishers, West Quincy Avenue, Denver, Colorado, U.S.A. (1991)