화학공학소재연구정보센터
Korean Chemical Engineering Research, Vol.42, No.1, 1-9, February, 2004
수소·연료전지 기술
Hydrogen & Fuel Cell Technology
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초록
수소에너지를 이용한 기술 중 연료전지 기술이 가장 효과적인 방법으로 인정되고 있다. 재래식 열연기관의 경우 일반적으로 33% 내지 35% 정도의 열효율로 전기를 얻을 수 있는데 반해 연료전지의 경우 전기생산 효율은 약 60%까지 올릴 수 있고 전체 에너지(전기와 열) 효율을 고려하면 85%까지도 생산이 가능한 상태이다. 더구나 연료전지의 경우 공해 배출이 거의 없다는 장점이 있다. 따라서 연료전지 기술은 21세기의 당면문제인 화석연료의 고갈과 환경오염 문제를 동시에 해결할 수 있는 대안으로 떠오르고 있다. 본 총설에서는 여러 가지 수소 제조 기술과 연료전지 기술 가운데 가장 실용화에 가깝고 실용화되면 배터리 대체, 소규모 주택용 및 건물용 전원, 자동차용 전원 등으로 사용할 수 있어서 경제 및 기술적인 파급효과가 큰 PEMFC와 DMFC에 대한 최근의 연구개발 경향을 정리하였다.
Among various technologies using hydrogen-energy, fuel cells have been considered as the most energy efficient technology. A conventional combustion-based power plant typically generates electricity at efficiencies of 33 to 35 percent, while fuel cell plants can generate electricity at efficiencies of up to 60 percent. When fuel cells are used to generate electricity and heat (co-generation), they can reach efficiencies of up to 85 percent. Moreover, fuel cells generate virtually zero pollution including greenhouse gases such as CO2. Therefore, the fuel cells are believed as a most promising alternative power producing technology, which can solve global problems facing 21st century such as exhaustion of fossil fuels and environmental pollution at the same time. In this review, recent trends in fuel cell R&D are summarized focusing on PEMFC and DMFC which are closest to the practical use and can be used for batteries, electrical power sources for automobiles and immobile structures such as buildings.
  1. US DOE, A National Vision of America's Transition to a Hydrogen Economy - To 2030 and Beyond, Feb. (2002)
  2. Business Communication Corp. (BCC), Chem. Mark. Repp, April 8, FR3 (2003)
  3. Kreuter W, Hofmann H, Int. J. Hydrog. Energy, 23(8), 661 (1998) 
  4. Schug CA, Int. J. Hydrog. Energy, 23(12), 1113 (1998) 
  5. Campillo B, Sebastian PJ, Gamboa SA, Albarran JL, Caballero LX, Mater. Sci. Eng., C19, 115 (2002)
  6. Hoor FS, Aravinda CL, Ahmed MF, Mayanna SM, J. Power Sources, 103(1), 147 (2001) 
  7. Vermeiren P, Adriansens W, Moreels JP, Leysen R, Int. J. Hydrog. Energy, 23(5), 321 (1998) 
  8. Kleinke MU, Knobel M, Bonugli LO, Teschke O, Int. J. Hydrog. Energy, 22(8), 759 (1997) 
  9. Appleby AJ, Electrocatal. Mod. Aspects Electrochem., 9, 369 (1974)
  10. Brooman EW, Kuhn AT, J. Electroanal. Chem., 49, 325 (1974) 
  11. Tilak BW, "Comprehensive Treaties of Electrochemistry," Vol. 5, Plenum (1982)
  12. Miles MH, J. Electroanal. Chem., 60, 89 (1975) 
  13. Commercial Brochures from Brown Boveri & Cie
  14. Commercial Brochures from Norsk Hydro Notodden Fabrikker
  15. Jensen FC, Schubert FH, "Hydrogen Energy," Part A, T.N. Vegiroglu, ed. Plenum Press, 425-439 (1975)
  16. Murray JN, Laskin JB, Kincaide WC, Proceedings of the Symposium on Industrial Water Electrolysis, Princeton, 78-4, 39-53 (1978)
  17. Murray JN, Laskin JB, Kincaide WC, Proceedings of the Symposium on Industrial Water Electrolysis, Princeton, 78-4, 117-127 (1978)
  18. Braun MJ, Proceedings of the Symposium on Industrial Water Electrolysis, Princeton, 78-4, 16-23 (1978)
  19. Christiansen K, Grundt T, Proceedings of the Symposium on Industrial Water Electrolysis, Princeton, 78-4, 24-38 (1978)
  20. Wuellenweber H, Mueller J, Proceedings of the Symposium on Industrial Water Electrolysis, Princeton, 78-4, 1 (1978)
  21. Giuffre L, Spaziant PM, Nidola A, Proceedings of the Symposium on Industrial Water Electrolysis, Princeton, 78-4, 190 (1978)
  22. Blomen LJMJ, Mugerwa MN, "Fuel Cell Systems," Plenum Press (1993)
  23. NAFION Product Bulletin, DuPont Company
  24. "Solid Polymer Electrolyte Water Electrolysis Technology Development for Large Scale Hydrogen Production," General Electric Company, DOE report No. DOE/ET/26202-1 (1981)
  25. Takenaka H, Torikai E, Kawami Y, Wakabayashi N, Int. J. Hydrog. Energy, 7(5), 397 (1982) 
  26. Funk JE, 10th World Hydrogen Energy Conference, Cocoa Beach, U.S.A. (1994)
  27. Isenberg AP, Proceedings of the Symposium on Electrode Materials and Processes for Energy Conversion and Storage, Princeton, 77-6, 682 (1978)
  28. Dutta S, Int. J. Hydrog. Energy, 15(6), 379 (1990) 
  29. Kobayashi T, Abe K, Ukyo Y, Matsumoto H, Solid State Ion., 138(3-4), 243 (2001) 
  30. Hartmut W, "Electrochemical Hydrogen Technologies," Elsevier (1990)
  31. Ioroi T, Yasuda K, Siroma Z, Fujiwara N, Miyazaki Y, J. Power Sources, 112(2), 583 (2002) 
  32. Ando Y, Tanaka T, Doi T, Takashima T, Energy Conv. Manag., 42(15-17), 1807 (2001) 
  33. Chen GY, Delafuente DA, Sarangapani S, Mallouk TE, Catal. Today, 67(4), 341 (2001) 
  34. Armor JN, Appl. Catal. A: Gen., 176(2), 159 (1999) 
  35. ICI Katalco Catalogue (1999)
  36. Kumar R, Agent O, "Summary Report on the IEA ANNEX XI PHASE II Workshop," 38 (2003)
  37. Heinzel A, Vogel B, Hubner P, J. Power Sources, 105(2), 202 (2002) 
  38. Avci AK, Trimm DL, Onsan ZI, Chem. Eng. J., 90(1-2), 77 (2002) 
  39. Freni S, Calogero G, Cavallaro S, J. Power Sources, 87(1-2), 28 (2000) 
  40. http://www.plugpower.com
  41. http://www.nuvera.com
  42. http://www.matthey.com
  43. Dudfield CD, Chen R, Adcock PL, J. Power Sources, 85(2), 237 (2000) 
  44. Dudfield CD, Chen R, Adcock PL, J. Power Sources, 86(1-2), 214 (2000) 
  45. Draft of Hydrogen, Fuel Cells & Infrastructure Technologies Program, U.S. DOE, EERE, June, 3 (2003)
  46. Manasilp A, Gulari E, Appl. Catal. B: Environ., 37(1), 17 (2002) 
  47. Echigo M, Tabata T, Appl. Catal. A: Gen., 251(1), 157 (2003) 
  48. Kahlich MJ, Gasteiger HA, Behm RJ, J. Catal., 182(2), 430 (1999) 
  49. Grot WG, Chem. Ind., 19, 647 (1985)
  50. Costamagna P, Srinivasan S, J. Power Sources, 102(1-2), 242 (2001) 
  51. Wakizoe M, Velev OA, Srinivasan S, Electrochim. Acta, 40(3), 335 (1995) 
  52. Kato H, "An Ion Exchange Membrane and Electrode Assembly for an Electrochemical Cell," U.S. Patent, No. 6,054,230 (2000)
  53. Savadogo O, J. New Mater. Electrochem. Syst., 1, 47 (1998)
  54. Kopitzke RW, Linkous CA, Anderson HR, Nelson GL, J. Electrochem. Soc., 147(5), 1677 (2000) 
  55. Wainright JS, Wang JT, Weng D, Savinell RF, Litt M, J. Electrochem. Soc., 142(7), L121 (1995) 
  56. Kawahara M, Rikukawa M, Sanui K, Ogata N, Solid State Ion., 136-137, 1193 (2000) 
  57. Mukerjee S, Srinivasan S, J. Electroanal. Chem., 357, 201 (1993) 
  58. Swette LL, LaConti AB, McCatty SA, J. Power Sources, 47, 343 (1994) 
  59. Mukerjee S, Srinivasan S, Soriaga MP, Mcbreen J, J. Electrochem. Soc., 142(5), 1409 (1995) 
  60. Verbeek H, Sachtler W, J. Catal., 42, 257 (1976) 
  61. Wang SR, Fedkiw PS, J. Electrochem. Soc., 139, 3151 (1992) 
  62. Bittins-Cattaneo B, Iwasita T, J. Electroanal. Chem., 238, 151 (1987) 
  63. Watanabe M, Motoo S, J. Electroanal. Chem., 60, 267 (1975) 
  64. Miura H, Gonzales R, J. Phys. Chem., 86(9), 1577 (1982) 
  65. Alerasool S, S, Gonzales RD, J. Catal., 124, 204 (1990) 
  66. Franaszczuk K, Sobkowski J, J. Electroanal. Chem., 327, 235 (1992) 
  67. Grgur BN, Zhuang G, Markovic NM, Ross PN, J. Phys. Chem. B, 101(20), 3910 (1997) 
  68. Grgur BN, Markovic NM, Ross PN, J. Phys. Chem. B, 102(14), 2494 (1998) 
  69. Gottesfeld S, Pafford J, J. Electrochem. Soc., 135, 2651 (1988) 
  70. Wilkinson DP, "Method and Apparatus for Oxidizing Carbon Monoxide in the Reactant Stream of an Electrochemical Fuel Cell," U.S. Patent, No. 5,432,021 (1995)
  71. Uribe A, Zawodzinski TA, Gottesfeld S, "Fuel Cell Anode Configuration for CO Tolerance," WO0036679 (1999)
  72. Toda T, Igarashi H, Uchida H, Watanabe M, J. Electrochem. Soc., 146(10), 3750 (1999) 
  73. Paffet MT, Beery GJ, Gottesfeld S, J. Electrochem. Soc., 135, 1431 (1988) 
  74. Beard BC, Ross PN, J. Electrochem. Soc., 130, 221 (1990)
  75. Raistrick ID, "Electrode Assembly for Use in a Solid Polymer Electrolyte Fuel Cell," U.S. Patent, No. 4,876,115 (1989)
  76. Dhar HP, "Near Ambient, Unhumidified Soild Polymer Fuel Cell," U.S. Patent, No. 5,318,863 (1994)
  77. Wood DL, Yi YS, Nguyen TV, Electrochim. Acta, 43(24), 3795 (1998) 
  78. Hentall PL, Lakeman JB, Mepsted GO, Adcock PL, Moore JM, J. Power Sources, 80(1-2), 235 (1999) 
  79. Hornung R, Kappelt G, J. Power Sources, 72(1), 20 (1998) 
  80. http://www.ballard.com/
  81. Smith MJ, "Hydrogen, Fuel Cells and Infrastructure Technologies Program," DOE 2002 Annual report, 267-268 (2002)
  82. Hogarth M, Christensen P, Hamnett A, Shukla A, J. Power Sources, 69(1-2), 113 (1997) 
  83. Chun BC, Reddington E, Sapienza A, Yu JS, Mallouk TE, "Combinatorial Discovery ane Optimization of anode Electrocatalysts for Direct Methanol Fuel Cell," Fuel Cell Seminar, November 16-19, 1-4 (1998)
  84. Sauk JH, Shul YG, Jung DH, Kim CS, Shin DR, Yang JC, HWAHAK KONGHAK, 37(1), 21 (1999)
  85. Kosek J, Cropely C, Hamdan M, Shramko A, "Recent Advances in Direct Methanol Fuel Cell at Giner, Inc." Fuel Cell Seminar, November 16-19, 693-694 (1998)
  86. Dolan G, "Methanol: The Consumer-Friendly Hydrogen Source," Fuel Cell Seminar, November 3-7, 676-679 (2003)
  87. http://www.fuelcells.org/
  88. Cox P, Cha SY, Attia A, "PolyFuel's Z1 Membrane and Catalyst Coatings to Improve the Fuel Cell Performance in Portable Power Applications," Fuel Cell Seminar, November 3-7, 977-980 (2003)
  89. Pavio J, "Performance and Design of a Reformed Hydrogen Fuel Cell Systems," Fuel Cell Seminar, November 3-7, 973-976 (2003)
  90. "MTI Micro Teams Up with Harris, Gillette/Duracell," Fuel Cells Bulletin, Issue, 12, 6 (2003)
  91. "Smart Fuel Cell Starts DMFC Series Production," Fuel Cells Bulletin, Issue 4, 4 (2002)
  92. "NEC Unweils Fully Integrated Fuel Cell Notebook PC," Fuel Cells Bulletin, Issue 8, 1 (2003)
  93. "Latest DMFC Prototypes From Toshiba, Hitach Focus on Catalyst," Fuel Cells Bulletin, Issue 12, 2 (2003)
  94. Maruyama R, Electrochim. Acta, 48(1), 85 (2002)