화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of the Korean Industrial and Engineering Chemistry, Vol.15, No.3, 265-277, May, 2004
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염료감응 태양전지
Dye-Sensitized Solar Cell
박남규†
  • 한국전자통신연구원 기반기술연구소, 대전 305-350
Nam-Gyu Park†
  • Basic Research Lab., Electronics and Telecommuications Research Isntitute (ETRI), Daejeon 305-350, Korea
E-mail:
초록
빛에너지를 전기에너지로 직접 변환 시키는 태양전지는 구성하는 물질에 따라 무기물 태양전지와 유기물 태양전지로 나눌 수 있다. 무기물 태양전지는 실리콘, 화합물반도체 등의 소재가 pn 접합으로 구성되어 있으며, 유기물 태양전지는 염료분자가 나노결정 입자 표면에 흡착되어 있는 것을 특징으로 하는 염료감응형과 donor-acceptor 특성의 유기(고)분자형으로 나눌 수 있다. 특히 염료감응형 유기태양전지는 높은 에너지변환 효율(약 11%)과 매우 낮은 제조가격 때문에 차세대 태양전지로 각광받고 있다. 본 총설에서는 염료감응 태양전지의 구조 및 작동원리를 설명하고, 최근의 연구개발 및 산업동향을 소개하였다.
Solar cells, converting directly light into electricity, can be categorized by materials comprising solar cells: inorganic-type and organic-type solar cells. Inorganic solar cells are composed of inorganic n-type and p-type materials such as silicon and compound semiconductors, where the structure of inorganic solar cell is typically built by pn junction. For the organic solar cells, there are two types; dye-sensitized solar cell and organic donor-acceptor solar cell. Dye-sensitized solar cell, consisting if nanocrystalline oxide film sensitized with dye molecule, redox electrolyte and metal counter electrode, is considered as alternative to conventional solar cells due to its high solar-to-electricity conversion efficiency (ca. 11%) and low cost. In this article, the structure, the operation principle and the recent R&D and industrial trends of dye-sensitized solar cells are discussed.
Keywords:dye-sensitized solar cell;photovoltaic
  1. http://www.eren.doe.gov/pv/history.html
  2. Chapin DM, Fuller CS, Pearson GL, J. Appl. Phys., 25, 676 (1954) 
  3. http://rredc.nrel.gov/solar/standards/am1.5
  4. Practical Handbook of Photovoltaics: Fundamentals and Applications, Eds., T. Markvart and L. Castaner, Elsevier, Oxford (2003)
  5. Kazmerski LL, Renewab. Sustain. Energy Rev., 1, 71 (1997) 
  6. Sariciftci NS, Braun D, Zhang C, Srdanov VI, Heeger AJ, Stucky G, Wudl F, Appl. Phys. Lett., 62, 585 (1993) 
  7. Yu G, Gao J, Hummelen JC, Wudl F, Heeger AJ, Science, 270(5243), 1789 (1995) 
  8. Halls JJM, Pichler K, Friend RH, Moratti SC, Holmes AB, Appl. Phys. Lett., 68, 3120 (1996) 
  9. Shaheen SE, Brabec CJ, Sariciftci NS, Padinger F, Fromherz T, Hummelen JC, Appl. Phys. Lett., 78, 841 (2001) 
  10. Yu G, Heeger AJ, J. Appl. Phys., 78, 4510 (1995) 
  11. Granstrom M, Petritsch K, Arias AC, Lux A, Andersson MR, Friend RH, Nature, 395(6699), 257 (1998) 
  12. Huynh WU, Dittmer JJ, Alivisatos AP, Science, 295, 2425 (2002) 
  13. O'Regan B, Gratzel M, Nature, 353, 737 (1991) 
  14. Nazeeruddin MK, Kay A, Humpbry-Baker R, Miiler E, Liska P, Vlachopoulos N, Gratzel M, J. Am. Chem. Soc., 115, 6382 (1993) 
  15. Benko G, Kallioinen J, Korppi-Tommola JEI, Yartsev AP, Sundstrom V, J. Am. Chem. Soc., 124(3), 489 (2002) 
  16. Asbury JB, Ellingson RJ, Ghosh HN, Ferrere S, Nozik AJ, Lian TQ, J. Phys. Chem. B, 103(16), 3110 (1999) 
  17. Tachibana Y, Moser JE, Gratzel M, Klug DR, Durrant JR, J. Phys. Chem., 100(51), 20056 (1996) 
  18. Hinsch A, Kroon JM, Kern R, Uhlendorf I, Holzbock J, Meyer A, Ferber J, Prog. Photovolt.: Res. Appl., 9, 425 (2001) 
  19. Kumar A, Santangelo PG, Lewis NS, J. Phys. Chem., 96, 834 (1992) 
  20. Huang SY, Schlichthorl G, Nozik AJ, Gratzel M, Frank AJ, J. Phys. Chem. B, 101(14), 2576 (1997) 
  21. Barbe CJ, Arendse F, Comte P, Jirousek M, Lenzmann F, Shklover V, Gratzel M, J. Am. Ceram. Soc., 80, 3157 (1997)
  22. Park NG, Schlichthorl G, van de Lagemaat J, Cheong HM, Mascarenhas A, Frank AJ, J. Phys. Chem. B, 103(17), 3308 (1999) 
  23. Bedja I, Hotchandani S, Kamat PV, J. Phys. Chem., 98(15), 4133 (1994) 
  24. Ferrere S, Zaban A, Gregg BA, J. Phys. Chem. B, 101(23), 4490 (1997) 
  25. O'Regan B, Schwartz DT, Zakeeruddin SM, Gratzel M, Adv. Mater., 12, 1263 (2000) 
  26. Bauer C, Boschloo G, Mukhtar E, Hagfeldt A, J. Phys. Chem. B, 105(24), 5585 (2001) 
  27. Lenzmann F, Krueger J, Burnside S, Brooks K, Gratzel M, Gal D, Ruhle S, Cahen D, J. Phys. Chem. B, 105(27), 6347 (2001) 
  28. Park NG, van de Lagemaat J, Frank AJ, J. Phys. Chem. B, 104(38), 8989 (2000) 
  29. Kay A, Gratzel M, Chem. Mater., 14, 2930 (2002) 
  30. Park NG, Kang MG, Ryu KS, Kim KM, Chang SH, J. Photochem. Photobiol. A-Chem., 161, 105 (2004) 
  31. Park NG, Langmuir, in press
  32. Gratzel M, Curr. Opin. Colloid Interface Sci., 4, 314 (1999) 
  33. Hara K, Sato T, Katoh R, Furube A, Ohga Y, Shinpo A, Suga S, Sayama K, Sugihara H, Arakawa H, J. Phys. Chem. B, 107(2), 597 (2003) 
  34. Wang P, Zakeerruddin SM, Moser JE, Nazeeruddin MK, Sekiguchi T, Gratzel M, Nature Mater., 2, 402 (2003) 
  35. Kim YG, Walker J, Samuelson LA, Kumar J, Nano Lett., 3, 523 (2003) 
  36. Nazeeruddin MK, Humphry-Baker R, Liska P, Gratzel M, J. Phys. Chem. B, 107(34), 8981 (2003) 
  37. Nogueira AF, De Paoli MA, Montanari I, Monkhouse R, Nelson J, Durrant JR, J. Phys. Chem. B, 105(31), 7517 (2001) 
  38. Kubo W, Kambe S, Nakade S, Kitamura T, Hanabusa K, Wada Y, Yanagida S, J. Phys. Chem. B, 107(18), 4374 (2003) 
  39. Wang P, Zakeeruddin SM, Comte P, Exnar I, Gratzel M, J. Am. Chem. Soc., 125(5), 1166 (2003) 
  40. O'Regan B, Schwartz DT, Chem. Mater., 10, 1501 (1998) 
  41. Tennakone K, Kumara GRRA, Kumarasinghe AR, Wijayantha KGU, Sirimanne PM, Semicond. Sci. Technol., 10, 1689 (1995) 
  42. Murakoshi K, Kogure R, Yanagida S, Chem. Lett., 5, 471 (1997) 
  43. Hagen J, Synth. Met., 89, 215 (1997) 
  44. Bach U, Lupo D, Comte P, Moser JE, Weissortel F, Salbeck J, Spreitzer H, Gratzel M, Nature, 395, 583 (1998) 
  45. Meng QB, Takahashi K, Zhang XT, Sutanto I, Rao TN, Sato O, Fujishima A, Watanabe H, Nakamori T, Uragami M, Langmuir, 19(9), 3572 (2003) 
  46. van de Lagemaat J, Park NG, Frank AJ, J. Phys. Chem. B, 104(9), 2044 (2000) 
  47. Eichberger R, Willig F, Chem. Phys., 141, 159 (1990) 
  48. Moser JE, Gratzel M, Durrant JR, Klug DR, Femtochemistry: Ultrafast Chemical and Physical Processes in Molecular Systems, World Scientific, River Edge, NJ (1996)
  49. Ellingson RJ, Asbury JB, Ferrere S, Ghosh HN, Sprague JR, Lian TQ, Nozik AJ, J. Phys. Chem. B, 102(34), 6455 (1998) 
  50. Schlichthorl G, Huang SY, Sprague J, Frank AJ, J. Phys. Chem. B, 101(41), 8141 (1997) 
  51. deJongh PE, Vanmaekelbergh D, Phys. Rev. Lett., 77, 3427 (1996) 
  52. Dejongh PE, Vanmaekelbergh D, J. Phys. Chem. B, 101(14), 2716 (1997) 
  53. Nelson J, Phys. Rev., B, Condens. Matter, 59, 15374 (1999)
  54. Kopidakis N, Schiff EA, Park NG, van de Lagemaat J, Frank AJ, J. Phys. Chem. B, 104(16), 3930 (2000) 
  55. Benkstein KD, Kopidakis N, van de Lagemaat J, Frank AJ, J. Phys. Chem. B, 107(31), 7759 (2003) 
  56. Ito S, Takeuchi T, Katayama T, Sugiyama M, Matsuda M, Kitamura T, Wada Y, Yanagida S, Chem. Mater., 15, 2824 (2003) 
  57. Doh JG, Hong JS, Vittal R, Kang MG, Park NG, Kim KJ, Chem. Mater., 16, 493 (2004) 
  58. Green MA, Emery K, King DL, Prog. Photovolt.: Res. Appl., 12, 55 (2004) 
  59. Shah A, Torres P, Tscharner R, Wyrsch N, Keppner H, Science, 285, 692 (1999) 
  60. Business Communications Company, Inc. (www.bccresearch.com) RE-038U Photovoltaics: Markets and Technologies, Published: August (2002)