회분식 반응기에서 폐윤활유 열분해 반응 특성

김승수; 윤왕래; 김성현

HWAHAK KONGHAK, Vol.37, No.6, 828-833, December, 1999

Export Citation

회분식 반응기에서 폐윤활유 열분해 반응 특성

The Pyrolysis of Waste Lubricating Oil in a Batch Reactor

김승수, 윤왕래, 김성현

초록

본 연구에서는 열중량분석법을 이용하여 1기압과 2기압에서 승온속도를 0.5, 1.0 및 2.0℃/min로 변화시키면서 폐윤활유의 열분해반응 속도 실험을 수행하였다. 전환율이 1%에서부터 100%일 때까지의 활성화에너지 및 반응차수를 구하였으며 반응기 급격하게 진행되는 구간에서 활성화에너지는 1기압일 대 점진적으로 증가하였고 2기압에서는 거의 변화가 없었다. 회분식 반응기에서 반응압력이 1기압과 2기압일 때 반응온도를 400-460℃로 변화시키면서 2시간동안 열분해반응 실험을 수행한 결과 반응온도가 증가할수록 생성된 열분해 오일의 양은 증가하지만 탄수소가 낮은 탄화수소화합물의 양은 감소하였다. 회분식반응기에서 폐윤활유의 최적 열분해 반응조건은 440℃, 1기압이였다.

Kinetic tests on pyrolysis of waste lubricating oil were carried out with thermo gravimetric technique at the heating rates of 0.5, 1.0, 2,0℃/min and pressure of 1 and 2 atm. The activation energy and the reaction order were determined at conversions of 1 to 100%. The activation energies were increased slowly at 1 atm, but took a constant value until a given degree of conversion at 2 atm. Waste lubrication oil was thermally cracked in semi-batch reactor of 400-460℃ at 1 and 2 atm for 2 hours. As the reaction temperature increased, the yields of products oils increased, but the product of light hydrocarbon oils decreased. The optimum temperature of pyrolysis of waste lubricating oil was 440℃ at 1 atm.

Keywords:Waste Lubricating Oil;Pyrolysis;Thermogravimetric Technique

[References]

Korea Lubricating Oil Industries Association Bulletin, 87(6), 32 (1998)
Reynolds JW, Whisman ML, Thompson CJ, Hydrocarb. Process., 56(9), 128 (1977)
Cotton FO, Whisman ML, Goetzinger JW, Reynolds JW, Hydrocarb. Process., 56(9), 131 (1977)
Linnard RE, Henton LM, Hydrocarb. Process., 58(9), 148 (1979)
Sequenira A, Sherman PB, Douciere JU, McBride EO, Hydrocarb. Process., 58(9), 155 (1979)
Bae JH, Chem. Ind. Technol., 12(1), 30 (1994)
Kim MS, Hwang JS, Kim HR, J. Environ. Sci. Health Part A-Toxic/Hazard. Subst. Environ. Eng., 32(4), 1015 (1997)
Hwang JS, Kim HR, Kim MS, Proceeding of the Fourth Japan-Korea Symposium on Separation Technology, 2, 681 (1996)
Bae JH, Min HH, Kwon SD, Chem. Ind. Technol., 16(1), 30 (1998)
Liebeskind JE, Chemtech, Sep., 537 (1973)
Mcintyre AD, Papic MM, Can. J. Chem. Eng., 52(April), 263 (1974)
Bouvier JM, Gelus M, Resources Conservation, 12, 77 (1986)
ASTM D 2887, "Standard Test Method for Boiling Range Distribution of Petroleum Fractions by Gas Chromatography,"
Liebman SA, Levy EJ, "Pyrolysis and GC in Polymer Analysis," Marcel Dekker, Inc., 191 (1984)
Friedman HL, J. Polym. Sci. C: Polym. Lett., 6, 183 (1963)
Liou TH, Chang FW, Lo JJ, Ind. Eng. Chem. Res., 36(3), 568 (1997)
Ozawa T, Bull. Chem. Soc. Jpn., 38, 1881 (1965)
Freeman ES, Carroll B, J. Phys. Chem., 62, 394 (1958)

[Referenced By]

[1] Korea Lubricating Oil Industries Association Bulletin, 87(6), 32 (1998)

[2] Reynolds JW, Whisman ML, Thompson CJ, Hydrocarb. Process., 56(9), 128 (1977)

[3] Cotton FO, Whisman ML, Goetzinger JW, Reynolds JW, Hydrocarb. Process., 56(9), 131 (1977)

[4] Linnard RE, Henton LM, Hydrocarb. Process., 58(9), 148 (1979)

[5] Sequenira A, Sherman PB, Douciere JU, McBride EO, Hydrocarb. Process., 58(9), 155 (1979)

[6] Bae JH, Chem. Ind. Technol., 12(1), 30 (1994)

[7] Kim MS, Hwang JS, Kim HR, J. Environ. Sci. Health Part A-Toxic/Hazard. Subst. Environ. Eng., 32(4), 1015 (1997)

[8] Hwang JS, Kim HR, Kim MS, Proceeding of the Fourth Japan-Korea Symposium on Separation Technology, 2, 681 (1996)

[9] Bae JH, Min HH, Kwon SD, Chem. Ind. Technol., 16(1), 30 (1998)

[10] Liebeskind JE, Chemtech, Sep., 537 (1973)

[11] Mcintyre AD, Papic MM, Can. J. Chem. Eng., 52(April), 263 (1974)

[12] Bouvier JM, Gelus M, Resources Conservation, 12, 77 (1986)

[13] ASTM D 2887, "Standard Test Method for Boiling Range Distribution of Petroleum Fractions by Gas Chromatography,"

[14] Liebman SA, Levy EJ, "Pyrolysis and GC in Polymer Analysis," Marcel Dekker, Inc., 191 (1984)

[15] Friedman HL, J. Polym. Sci. C: Polym. Lett., 6, 183 (1963)

[16] Liou TH, Chang FW, Lo JJ, Ind. Eng. Chem. Res., 36(3), 568 (1997)

[17] Ozawa T, Bull. Chem. Soc. Jpn., 38, 1881 (1965)

[18] Freeman ES, Carroll B, J. Phys. Chem., 62, 394 (1958)