An increasing number of single-particle measurements show that organic and inorganic constituents of the atmospheric aerosol are internally mixed within the particles. Therefore, the phases of the aerosol will be influenced by both mixing of the organic substances with each other and mixing between organic and inorganic constituents. In this work, the mixing properties of the organic aerosol fractions have been investigated theoretically and experimentally with respect to melting and deliquescence. We show that a liquid (or an amorphous solid) is the thermodynamically stable phase-even in the absence of water as a solvent-provided that a sufficiently high number of miscible components are present. Furthermore, we show experimentally that the deliquescence relative humidity of aqueous solutions of dicarboxylic acids decreases with an increasing number of components present in the solution. A five-component mixture consisting of malic, malonic, maleic, glutaric, and methylsuccinic acids deliquesces at a relative humidity (RH) as low as 45.4% RH, while the pure dicarboxylic acids exhibit deliquescence points between 72 and 96% RH. A further reduction of the deliquescence relative humidity is observed when an inorganic salt is added to the dicarboxylic acid five-component mixture. For NaCl, deliquescence of the eutonic composition occurred at 41.3%, for ammonium sulfate at 36.4%, and for ammonium nitrate even at 27.1 % RH. Interactions between the solutes lead to either higher or lower solubilities in the multicomponent mixture as compared to the respective single-component aqueous solutions. In the mixed dicarboxylic acids/inorganic salt solutions, the solubilities of ammonium nitrate and sulfate are increased by similar to40%, the one of sodium chloride is decreased by a similar amount. In summary, these mixing properties suggest that small fractions of organic species prevent tropospheric aerosols from becoming fully solid, and the organic fraction may even stay fully liquid irrespective of tropospheric humidity.