화학공학소재연구정보센터
Journal of Applied Polymer Science, Vol.92, No.5, 2995-3001, 2004
Radiation synthesis and environmental responsiveness of semi-interpenetrating polymer networks composed of poly(dimethyl-aminoethyl methacrylate) and poly(ethylene oxide)
Semi-interpenetrating polymer networks (semi-IPNs) composed of poly(dimethyl-aminoethyl methacrylate) (PDMAEMA) and poly(ethylene oxide) (PEO) were synthesized by gamma-radiation; three semi-IPNs with 80: 20, 90: 10, and 95: 5 weight ratios of DMAEMA/PEO were obtained by use of this technique. The gel-dose curves showed that the hydrogels were characterized by a structure typical of semi-IPNs and the results of elemental analysis supported this point. The temperature-induced phase transition of semi-IPNs with the composition of 95: 5 was still retained, with the lower critical solution temperature of PDMAEMA shifting from 40 to 27degreesC. The temperature sensitivity of the other two semi-IPNs gradually disappeared. The pH sensitivity of three semi-IPNs was still retained but the pH shifted slightly to lower values with increasing PEO content in the semi-IPNs. The effect of PEO content in semi-IPNs on their environmental responsiveness was discussed. (C) 2004 Wiley Periodicals, Inc.