[Ag-6(PMo10V2O40)](CH3COO)center dot 8H(2)O: A 3D macrocationic polyoxometallic Keggin complex

Liu FX; Marchal-Roch C; Bouchard P; Marrot J; Simonato JP; Herve G; Secheresse F

Inorganic Chemistry, Vol.43, No.7, 2240-2242, 2004

Liu FX, Marchal-Roch C, Bouchard P, Marrot J, Simonato JP, Herve G, Secheresse F

Silver atoms and strongly interlinking Keggin units ensure the tridimensionnal macrocationic structure of [Ag-6(PMo10V2O40)](CH3COO).8H(2)O, which catalyzes O-2-based oxidation of p-methoxy-toluene in acetic acid by air.