Fly ashes resulting from the combustion of fuel containing high concentrations of vanadium that can be slightly removed by water and more efficiently by alkaline or acid solutions. This uncontrolled release can contaminate water sources and requires appropriate storage of fly ashes. This study investigated the possibility of cleaning the ashes by leaching the material and recovering vanadium by solvent extraction (for metal concentration solutions higher than 200 mg V L-1) using several amine extractants (Primene JM-T, Amberlite LA-2, Alamine 336, and Alamine 304), a quaternary ammonium salt (Aliquat 336), and by a sorption process (for low-metal concentration solutions) using chitosan. Extraction and stripping were investigated with liquid extractants and showed that Aliquat 336 was the best of these extractants. However, since Aliquat 336 exhibits a greater difficulty at stripping, secondary or tertiary amine extractants appear more suited for the extraction process. Vanadium sorption occurs on chitosan through anion exchange with a maximum sorption capacity of 400 to 450 mg V g(-1) at pH 3. The treatment of acid leachates with chitosan does not appear possible, since it requires a pH control to pH 3, which precipitates ferric ions and coprecipitates vanadium. Alternative routes could be the alkaline leaching of fly ashes and a further pH control.