Kinetic and isotopic tracer and exchange measurements were used to determine the identity and reversibility of elementary steps required for CH4 reforming reactions on Ru-based catalyst. These studies provide a simple mechanistic picture and a unifying kinetic treatment for CH4/CO2 and CH4/H2O reforming reactions and CH4 decomposition. Forward kinetic rates were measured from net rates by correcting for the approach to equilibrium, after ruling out transport artifacts using pellet and bed dilution tests. The kinetic processes involved are exclusively limited by C-H bond activation, and CH4 reaction rates are unaffected by the identity or the concentration of co-reactants (H2O, CO2). Similar normal kinetic isotopic effects (k(C-H)/k(C-D) = 1.40-1.51) were measured for CO2 reforming, H2O reforming, and CH4 decomposition, consistent with kinetically relevant C-H bond activation steps. The ratio of CH4/CD4 cross-exchange to methane chemical conversion rates during the reaction of CO2 reforming with CH4-CD4 mixtures was 0.05, suggesting that steps involving C-H bond activation are essentially irreversible. Binomial D-atom distributions in dihydrogen and water were obtained during reactions of CH4/CO2/D-2 Mixtures, and their D-contents were identical to those expected from complete equilibration between D-2 and H-atoms from reacted CH4, indicating that H-OH and H-H recombination steps are quasi-equilibrated. Reactions of (CH4)-C-12/(CO2)-C-12/(CO)-C-13 mixtures gave identical C-13 contents in CO and CO2, even far away from the CO2 reforming equilibrium; thus, CO2 activation is reversible and quasi-equilibrated during CO2 reforming on Ru-based catalysts, as expected from the kinetic irrelevance of co-reactant activation steps. These conclusions suggest that water-gas shift reactions are also equilibrated, as confirmed by chemical analyses of reaction products. Forward CH4 turnover rates increased with increasing Ru dispersion, but they were essentially unaffected by the identity of the support. This behavior reflects the higher reactivity of coordinatively unsaturated surface atoms, prevalent in small Ru clusters, for C-H bond activation reactions, as previously inferred from the effect of crystal orientation on CH4 activation rates.