Inorganic Chemistry, Vol.43, No.13, 3801-3803, 2004
Mixed carboxylate-bridged dimanganese(II/Ill) compounds prepared by an O-2-dependent oxidative cleavage of ketones
The structure of an O-2-sensitive Mn(II)Mn(II) complex with an unsymmetrical perchlorate bridge is reported. This complex promotes an O-2-dependent oxidative cleavage of ketones giving mixed carboxylate complexes.