Mixing Properties of Isopropyl Acetate+Aromatic Hydrocarbons at 298.15 K: Density, Refractive Index and Isentropic Compressibility

J.M. Resa; C. Gonzalez; E. Diez; R. G. Concha; M. Iglesias

Korean Journal of Chemical Engineering, Vol.21, No.5, 1015-1025, September, 2004

J.M. Resa^†, C. Gonzalez, E. Diez, R. G. Concha, and M. Iglesias¹

Dpto. de Ingenieria Qu´imica, Universidad del Pais Vasco, Apto. 450, Vitoria, Spain
¹Departament d’Enginyeria Qu´imica, Escola T`ecnica Superior d’Enginyeria Qu´imica, Universitat Rovira i Virgili, Avinguda Pa"isos Catalans 26, Campus Sescelades, 43007 Tarragona, Spain

E-mail:

We present new experimental data of density, refractive index and speed of sound for the binaries of isopropyl acetate+(toluene, ethylbenzene, p-xylene, mesitylene, isopropylbenzene, butylbenzene, isobutylbenzene, or t-butylbenzene) at T=298.15 K and standard conditions, and the corresponding computed derived magnitudes (change of isentropic compressibility, change of isentropic compressibility, change of refractive index on mixing, and excess molar volume). The mixtures show a clear expansive tendency for the highest molar weight compounds and the steric hindrance role of the aromatic chemicals being analyzed to the light of the non-ideality on mixing. A good agreement among experimental data and the values extimated by theoretical procedures was obtained.

Keywords:Excess Volumes;Change of Refractive Indices;Change of Isentropic Compressibility;Isopropyl Acetate;Aromatic Hydrocarbon;Prediction

[References]

Danusso F, Atti Accad. Nazl. Lincei, 10, 235 (1951)
Iglesias M, Orge B, Tojo J, Fluid Phase Equilib., 126(2), 203 (1996)
Jacobson B, Acta Chemica Scandinavica, 6, 1485 (1952)
Kay WE, J. Ind. Eng. Chem., 28, 1014 (1936)
Marquardt DW, J. Soc. Indust. Appl. Math., 11, 431 (1963)
Nomoto O, J. Phys. Soc. Jpn., 13(12), 1528 (1958)
Nutsch-kuhnkies R, Acustica, 15(1), 383 (1965)
Poling BE, Prausnitz JM, O Connell JP, "The Properties of Gases and Liquids (5th ed.)," McGraw-Hill, Internationals Editions, USA (2001)
Prausnitz JM, Gunn RD, AIChE J., 4, 430 (1958)
Rackett HG, J. Chem. Eng. Data, 15(4), 514 (1970)
Redlich O, Kister AT, Ind. Eng. Chem., 40, 345 (1948)
Resa JM, Gonzalez C, Lanz J, Mtz de Ilarduya JA, J. of Thermal Anal. and Calorimetry, 52(3), 895 (1998)
Resa JM, Iglesias M, Gonzalez C, Lanz J, de Ilarduya JAM, J. Chem. Thermodyn., 33(7), 723 (2001)
Resa JM, Gonzalez C, de Landaluce O, Lanz J, J. Chem. Thermodyn., 34(7), 995 (2002)
Resa JM, Gonzalez C, Prieto S, Diez E, Iglesias M, Korean J. Chem. Eng. (2003)
Resa JM, Gonzalez C, Concha RG, Iglesias M, Int. J. Thermophys. (2003)
Resa JM, Gonzalez C, Concha RG, Iglesias M, Physics and Chemistry of Liquids (2003)
Resa JM, Gonzalez C, Concha RG, Iglesias M, Physics and Chemistry of Liquids (2003)
Riddick JA, Bunger WB, Sakano TK, "Organic Solvents," Wiley-Interscience, USA (1986)
Sastry NV, Patel MC, J. Chem. Eng. Data, 48(4), 1019 (2003)
Schaaffs W, "Molekularakustic; eine Einfuehrung in die Zusammen haenge zwischen Ultraschall und Molekuelstruktur in Fluessigkeiten und Gasen," Springer Verlag: Bonn, 497 (1963)
Schaaffs W, Acustica, 33(4), 272 (1975)
Spencer CF, Danner RP, J. Chem. Eng. Data, 17(2), 236 (1972)

[1] Danusso F, Atti Accad. Nazl. Lincei, 10, 235 (1951)

[2] Iglesias M, Orge B, Tojo J, Fluid Phase Equilib., 126(2), 203 (1996)

[3] Jacobson B, Acta Chemica Scandinavica, 6, 1485 (1952)

[4] Kay WE, J. Ind. Eng. Chem., 28, 1014 (1936)

[5] Marquardt DW, J. Soc. Indust. Appl. Math., 11, 431 (1963)

[6] Nomoto O, J. Phys. Soc. Jpn., 13(12), 1528 (1958)

[7] Nutsch-kuhnkies R, Acustica, 15(1), 383 (1965)

[8] Poling BE, Prausnitz JM, O Connell JP, "The Properties of Gases and Liquids (5th ed.)," McGraw-Hill, Internationals Editions, USA (2001)

[9] Prausnitz JM, Gunn RD, AIChE J., 4, 430 (1958)

[10] Rackett HG, J. Chem. Eng. Data, 15(4), 514 (1970)

[11] Redlich O, Kister AT, Ind. Eng. Chem., 40, 345 (1948)

[12] Resa JM, Gonzalez C, Lanz J, Mtz de Ilarduya JA, J. of Thermal Anal. and Calorimetry, 52(3), 895 (1998)

[13] Resa JM, Iglesias M, Gonzalez C, Lanz J, de Ilarduya JAM, J. Chem. Thermodyn., 33(7), 723 (2001)

[14] Resa JM, Gonzalez C, de Landaluce O, Lanz J, J. Chem. Thermodyn., 34(7), 995 (2002)

[15] Resa JM, Gonzalez C, Prieto S, Diez E, Iglesias M, Korean J. Chem. Eng. (2003)

[16] Resa JM, Gonzalez C, Concha RG, Iglesias M, Int. J. Thermophys. (2003)

[17] Resa JM, Gonzalez C, Concha RG, Iglesias M, Physics and Chemistry of Liquids (2003)

[18] Resa JM, Gonzalez C, Concha RG, Iglesias M, Physics and Chemistry of Liquids (2003)

[19] Riddick JA, Bunger WB, Sakano TK, "Organic Solvents," Wiley-Interscience, USA (1986)

[20] Sastry NV, Patel MC, J. Chem. Eng. Data, 48(4), 1019 (2003)

[21] Schaaffs W, "Molekularakustic; eine Einfuehrung in die Zusammen haenge zwischen Ultraschall und Molekuelstruktur in Fluessigkeiten und Gasen," Springer Verlag: Bonn, 497 (1963)

[22] Schaaffs W, Acustica, 33(4), 272 (1975)

[23] Spencer CF, Danner RP, J. Chem. Eng. Data, 17(2), 236 (1972)