Phase Evolution of an Al-B-N Nanocomposite Prepared from a Preceramic Polymer Mixture

Jong-Kyu Jeon; Christel Gervais; Florence Babonneau; Dong-pyo Kim

Journal of Industrial and Engineering Chemistry, Vol.10, No.5, 717-721, September, 2004

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Phase Evolution of an Al-B-N Nanocomposite Prepared from a Preceramic Polymer Mixture

Jong-Kyu Jeon, Christel Gervais¹, Florence Babonneau¹, and Dong-pyo Kim^†

Department of Fine Chemical Engineering & Chemistry, Chungnam National University, Daejeon 305-764, Korea
¹Laboratorie de Chimie de la Matiere Condensee, UMR-CNRS 7574, Universite Pierre et Marie Curie, 4 Place Jussieu, 75252 Paris, France

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The phase evolution of an Al-B-N ternary system was studied using mixture of nanosized Al metal powder and polyborazine, as a source of boron and nitrogen, which was pyrolyzed at 1200℃ in an Ar atmosphere. The precursor system initially formed an Al/AlN mixture when annealed at 700℃, and then it converted to AlN/BN/ AlB₂ nanocomposite phase at 900℃. Interestingly, we observed that, at 1200℃, the AlB₂ formed was reduced partly to Al metal embedded in the nanocomposite phase. The systems were investigated using XRD, XRS, and both²⁷Al and ¹¹B solid state NMR spectroscopies.

Keywords:Al-B-N nanocomposite;Al metal;polyborazine

[References]

Rockens W, Roesky HW, Adv. Mater., 5, 445 (1993)
Kim DP, Economy J, Chem. Mater., 5, 1216 (1993)
Riedel R, Adv. Mater., 6, 549 (1994)
Bae DS, Han KS, Choi SH, J. Kor. Ceram. Soc., 33, 524 (1996)
Moon KT, Jeon JK, Kim YJ, Kim DP, Scr. Mater., 44, 2111 (2001)
Rizzoli C, Salamakha PS, Sologub OL, Bocelli G, J. Alloy. Compd., 343, 135 (2002)
Massalski TV, Subramanian PR, Okamoto H, Kacprzak I, in Binary Alloy Phase Diagrams, 2nd Ed., ASM International, Materials Park, OH (1990)
Pearson's Handbook of Crystallographic Data of Intermetallic Phases, P. Villars, L. D. Calvert Eds., ASM International, Materials Park, OH (1985)
Villars P, Prince A, Okamoto H, Handbook of Ternary Alloy Phase Diagrams, ASM International, Materials Park, OH (1995)
Will G, Acta Cryst., 23, 1071 (1967)
Higashi I, Sakurai T, Atoda T, J. Solid State Chem., 20, 67 (1977)
Kohn IA, Eckart DW, Anal. Chem., 32, 296 (1960)
Higashi I, J. Solid State Chem., 47, 333 (1983)
Higashi I, Iwamasaki H, Ito T, Lundstrom T, Okada S, Tergenins LE, J. Solid State Chem., 82, 230 (1989)
Deppisch C, Liu G, Hall A, Xu Y, Zangvil A, Shang JK, Economy J, J. Mater. Res., 13, 3485 (1998)
Moon KT, Min DS, Kim DP, Bull. Korean Chem. Soc., 19, 222 (1998)
Man PP, Mol. Phys., 78, 307 (1993)
Massiot D, Mller D, Hbert T, Schneider M, Kentgens AP, Cot B, Coutures JP, Gessner W, Solid State Nucl. Magn. Reson., 5, 175 (1995)
Massiot D, Fayon F, Capron M, King I, LeCalve S, Alonso B, Durand J, Bujoli B, Ghan Z, Hoatson G, Magn. Reson. Chem., 20, 70 (2002)
Bastow TJ, Smith ME, J. Phys. Condens. Matter, 7, 4929 (1995)
Braniger T, Kempgens P, Harris RK, Howes AP, Liddel K, Thompson DP, Solid State Nucl. Magn. Reson., 23, 62 (2003)
Beck SH, Suh BJ, Paravini E, Borsa F, Barnes RG, Budko SL, Canfield PC, Phys. Rev., B, Condens. Matter, 66, 140514 (2002)
Gervais C, Maquet J, Babonneau F, Duriez C, Framery E, Vaultier M, Florian P, Massiot D, Chem. Mater., 13, 1700 (2001)
Rebholz C, Schneider JM, Voevodin AA, Steinebrunner J, Charitidis C, LogoThetidis S, Leyland A, Matthews A, Surf. Coat. Technol., 113, 126 (1999)
Rebholz C, Leyland A, Schneider JM, Voevodin AA, Matthews A, Surf. Coat. Technol., 120, 412 (1999)

[Referenced By]

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[1] Rockens W, Roesky HW, Adv. Mater., 5, 445 (1993)

[2] Kim DP, Economy J, Chem. Mater., 5, 1216 (1993)

[3] Riedel R, Adv. Mater., 6, 549 (1994)

[4] Bae DS, Han KS, Choi SH, J. Kor. Ceram. Soc., 33, 524 (1996)

[5] Moon KT, Jeon JK, Kim YJ, Kim DP, Scr. Mater., 44, 2111 (2001)

[6] Rizzoli C, Salamakha PS, Sologub OL, Bocelli G, J. Alloy. Compd., 343, 135 (2002)

[7] Massalski TV, Subramanian PR, Okamoto H, Kacprzak I, in Binary Alloy Phase Diagrams, 2nd Ed., ASM International, Materials Park, OH (1990)

[8] Pearson's Handbook of Crystallographic Data of Intermetallic Phases, P. Villars, L. D. Calvert Eds., ASM International, Materials Park, OH (1985)

[9] Villars P, Prince A, Okamoto H, Handbook of Ternary Alloy Phase Diagrams, ASM International, Materials Park, OH (1995)

[10] Will G, Acta Cryst., 23, 1071 (1967)

[11] Higashi I, Sakurai T, Atoda T, J. Solid State Chem., 20, 67 (1977)

[12] Kohn IA, Eckart DW, Anal. Chem., 32, 296 (1960)

[13] Higashi I, J. Solid State Chem., 47, 333 (1983)

[14] Higashi I, Iwamasaki H, Ito T, Lundstrom T, Okada S, Tergenins LE, J. Solid State Chem., 82, 230 (1989)

[15] Deppisch C, Liu G, Hall A, Xu Y, Zangvil A, Shang JK, Economy J, J. Mater. Res., 13, 3485 (1998)

[16] Moon KT, Min DS, Kim DP, Bull. Korean Chem. Soc., 19, 222 (1998)

[17] Man PP, Mol. Phys., 78, 307 (1993)

[18] Massiot D, Mller D, Hbert T, Schneider M, Kentgens AP, Cot B, Coutures JP, Gessner W, Solid State Nucl. Magn. Reson., 5, 175 (1995)

[19] Massiot D, Fayon F, Capron M, King I, LeCalve S, Alonso B, Durand J, Bujoli B, Ghan Z, Hoatson G, Magn. Reson. Chem., 20, 70 (2002)

[20] Bastow TJ, Smith ME, J. Phys. Condens. Matter, 7, 4929 (1995)

[21] Braniger T, Kempgens P, Harris RK, Howes AP, Liddel K, Thompson DP, Solid State Nucl. Magn. Reson., 23, 62 (2003)

[22] Beck SH, Suh BJ, Paravini E, Borsa F, Barnes RG, Budko SL, Canfield PC, Phys. Rev., B, Condens. Matter, 66, 140514 (2002)

[23] Gervais C, Maquet J, Babonneau F, Duriez C, Framery E, Vaultier M, Florian P, Massiot D, Chem. Mater., 13, 1700 (2001)

[24] Rebholz C, Schneider JM, Voevodin AA, Steinebrunner J, Charitidis C, LogoThetidis S, Leyland A, Matthews A, Surf. Coat. Technol., 113, 126 (1999)

[25] Rebholz C, Leyland A, Schneider JM, Voevodin AA, Matthews A, Surf. Coat. Technol., 120, 412 (1999)