Multi-component Ion Exchange Kinetics with PAN-KCoFC Composite Ion Exchanger

Jei-Kwon Moon; Eil-Hee Lee; Yoon-Ju Han; Byung-Chul Lee; Hyung-Tae Kim

Korean Journal of Chemical Engineering, Vol.22, No.1, 127-132, January, 2005

DOI10.1007/BF02701474 Export Citation

Multi-component Ion Exchange Kinetics with PAN-KCoFC Composite Ion Exchanger

Jei-Kwon Moon^†, Eil-Hee Lee , Yoon-Ju Han, Byung-Chul Lee¹, and Hyung-Tae Kim²

Korea Atomic Energy Research Institute, Korea
¹Dept. of Chemical Engineering, Hannam University, Daejeon 306-010, Korea
²Korean Research Institute of Chemical Technology, Daejeon 305-761, Korea

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An ion exchange kinetic study was performed using PAN-KCoFC for removal of cesium ion from mixed solution of Cs, Sr, Ni and Ba ions. Uptake curves were obtained for a multi-component ion exchange system as well as binary system. A PAN-KCoFC composite ion exchanger showed higher selectivity for Cs ion over the Sr, Ba, Ni ions. A homogeneous model could predict accurately the uptake curve for both the binary and multi-component systems. Solid phase effective pore diffusivities obtained by modeling ranged between 10-5 cm2/min and 10-6 cm2/min.

Keywords:Composite Ion Exchanger;Ion Exchange Kinetics;Cesium Ion;Radionuclides;PAN;KCoFC

[References]

Anthony RG, Philip CV, Dosch RG, Waste Manage., 13, 503 (1993)
Ernest MV, Bibler JP, Whitley RD, Wang NH, Ind. Eng. Chem. Res., 36(7), 2775 (1997)
Enarsson A, Landgren A, Liljenzin JO, Skalberg M, Spjuth L, Gudowski W, Wallenius J, "Partitioning and Transmutation (P&T) 1997", SKB annual Report, TR-98-14 (1998)
Gu D, Nguyen L, Philip CV, Huckman ME, Anthony RG, Miller JE, Trudell DE, Ind. Eng. Chem. Res., 36(12), 5377 (1997)
John J, Sebesta F, Motl A, Radiochim. Acta, 78, 131 (1997)
Kim HT, Lee CH, Shul YG, Mon JK, Lee EH, Sep. Sci. Technol., 38(3), 695 (2003)
Kim HT, Shul YG, Moon JK, Jung CH, Lee EH, Czech. J. Phys., 53, 487 (2003)
Marageh MG, Husain SW, Khanchi AR, Appl. Radiat. Isot., 50, 459 (1999)
Mardan A, Rumana A, Mehmood A, Raza SM, Ghaffar A, Sep. Purif. Technol., 16, 147 (1999)
Mimura H, Lehto J, Harjula R, J. Nucl. Sci. Technol., 34(5), 484 (1997)
Mimura H, Letho J, Harjula R, J. Nucl. Sci. Technol., 34(6), 582 (1997)
Moon JK, Lee EH, Kim HT, Korean J. Chem. Eng., 21 (2004)
Moon JK, Kim KW, Jung CH, Lee EH, Shul YG, J. Radioanal. Nucl. Chem., 246(2), 299 (2000)
Moon JK, Jung CH, Lee EH, Kim HT, Shul YG, Korean J. Chem. Eng., 19(5), 838 (2002)
Moon JK, Kim HT, Shul YG, Lee EH, Yoo JH, HWAHAK KONGHAK, 38(6), 847 (2000)
Rao SVS, Lal KB, Narasimhan SV, Ahmed J, J. Radioanal. Nucl. Chem., 240(1), 269 (1999)
Rice RG, Do DD, Applied Mathematics and Modeling for Chemical Engineers, John Wiley & Sons, New York (1995)
Robinson SM, Arnold WD, Byers CH, AIChE J., 40(12), 2045 (1994)
Ruthven DM, Loughlin KF, Can. J. Chem. Eng., 50, 550 (1972)
Ruthven DM, Principle of Adsorption and Adsorption Processes, Wiley, New York (1984)
Sebesta F, John J, "An Overview of the Development, Testing, and Application of Composite Absorbers", LA-12875-MS (1995)
Sinha PK, Panicker PK, Amalraj RV, Krishnasamy V, Waste Manage., 15(2), 149 (1995)
Sinha PK, Lal KB, Panicker PK, Amalraj RV, Krishnasamy V, Ind. J. Chem., 33A, 924 (1994)
Tarasevich YI, Kardasheva MV, Polyakov VE, Colloid J., 59(6), 754 (1997)
Villadsen J, Michelsen ML, Solution of Differential Equation Models by Polynomial Approximation, Prentice-Hall, Englewood Cliff, NJ (1978)

[Referenced By]

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[1] Anthony RG, Philip CV, Dosch RG, Waste Manage., 13, 503 (1993)

[2] Ernest MV, Bibler JP, Whitley RD, Wang NH, Ind. Eng. Chem. Res., 36(7), 2775 (1997)

[3] Enarsson A, Landgren A, Liljenzin JO, Skalberg M, Spjuth L, Gudowski W, Wallenius J, "Partitioning and Transmutation (P&T) 1997", SKB annual Report, TR-98-14 (1998)

[4] Gu D, Nguyen L, Philip CV, Huckman ME, Anthony RG, Miller JE, Trudell DE, Ind. Eng. Chem. Res., 36(12), 5377 (1997)

[5] John J, Sebesta F, Motl A, Radiochim. Acta, 78, 131 (1997)

[6] Kim HT, Lee CH, Shul YG, Mon JK, Lee EH, Sep. Sci. Technol., 38(3), 695 (2003)

[7] Kim HT, Shul YG, Moon JK, Jung CH, Lee EH, Czech. J. Phys., 53, 487 (2003)

[8] Marageh MG, Husain SW, Khanchi AR, Appl. Radiat. Isot., 50, 459 (1999)

[9] Mardan A, Rumana A, Mehmood A, Raza SM, Ghaffar A, Sep. Purif. Technol., 16, 147 (1999)

[10] Mimura H, Lehto J, Harjula R, J. Nucl. Sci. Technol., 34(5), 484 (1997)

[11] Mimura H, Letho J, Harjula R, J. Nucl. Sci. Technol., 34(6), 582 (1997)

[12] Moon JK, Lee EH, Kim HT, Korean J. Chem. Eng., 21 (2004)

[13] Moon JK, Kim KW, Jung CH, Lee EH, Shul YG, J. Radioanal. Nucl. Chem., 246(2), 299 (2000)

[14] Moon JK, Jung CH, Lee EH, Kim HT, Shul YG, Korean J. Chem. Eng., 19(5), 838 (2002)

[15] Moon JK, Kim HT, Shul YG, Lee EH, Yoo JH, HWAHAK KONGHAK, 38(6), 847 (2000)

[16] Rao SVS, Lal KB, Narasimhan SV, Ahmed J, J. Radioanal. Nucl. Chem., 240(1), 269 (1999)

[17] Rice RG, Do DD, Applied Mathematics and Modeling for Chemical Engineers, John Wiley & Sons, New York (1995)

[18] Robinson SM, Arnold WD, Byers CH, AIChE J., 40(12), 2045 (1994)

[19] Ruthven DM, Loughlin KF, Can. J. Chem. Eng., 50, 550 (1972)

[20] Ruthven DM, Principle of Adsorption and Adsorption Processes, Wiley, New York (1984)

[21] Sebesta F, John J, "An Overview of the Development, Testing, and Application of Composite Absorbers", LA-12875-MS (1995)

[22] Sinha PK, Panicker PK, Amalraj RV, Krishnasamy V, Waste Manage., 15(2), 149 (1995)

[23] Sinha PK, Lal KB, Panicker PK, Amalraj RV, Krishnasamy V, Ind. J. Chem., 33A, 924 (1994)

[24] Tarasevich YI, Kardasheva MV, Polyakov VE, Colloid J., 59(6), 754 (1997)

[25] Villadsen J, Michelsen ML, Solution of Differential Equation Models by Polynomial Approximation, Prentice-Hall, Englewood Cliff, NJ (1978)