Color-matching functions may be considered dimension reduction functions that project a spectral reflectance function into the desired space of colors. Using a gray metameric pair with maximal spectral difference we compare the abilities of various human and other observers with regard to the transition wavelengths for that metameric pair. Transition wavelengths are shown to be a convenient tool for comparing and classifying observers regardless of the number of dimension reduction functions. Four human observers were identified as differing in a comparable manner from the CIE 2degrees standard observer. (C) 2004 Wiley Periodicals, Inc.