Journal of Polymer Science Part A: Polymer Chemistry, Vol.42, No.10, 2474-2482, 2004
(13)Carbon nuclear magnetic resonance of ethylene-propylene-1-hexene terpolymers
We report the complete C-13 NMR characterization of a series of ethylenepropylene-1-hexene terpolymers obtained with the metallocenic system rac-ethylene bis-indenyl zirconium dichloride, with different comonomer ratios. A detailed study of C-13 NMR chemical shifts, triad sequence distributions, monomer-average sequence lengths, and reactivity ratios for these terpolymers is presented. (C) 2004 Wiley Periodicals, Inc.
Keywords:ethylene-propylene-1-hexene terpolymers;C-13 NMR;reactivity ratios;polyolefins;microstructure;NMR