Journal of Polymer Science Part A: Polymer Chemistry, Vol.42, No.16, 4028-4035, 2004
Free radical and thermal curing of terpyridine-modified terpolymers
Terpolymers bearing terpyridine as well as (meth)acrylates as free radical curable groups (UV-curing) or hydroxyl groups (thermal curing with bis-isocyanates) were synthesized and characterized using H-1 NMR, IR and UV-vis spectroscopy as well as GPC. Subsequently, the ability of covalent crosslinking via the UV-initiated polymerization of the acrylate groups was investigated. Moreover, the thermal covalent crosslinking via the reaction of hydroxyl functionalized terpolymer and bis-isocyanate compounds could be successfully achieved. (C) 2004 Wiley Periodicals, Inc.
Keywords:crosslinking;poly(methyl methacrylate);UV-curing;thermal curing;supramolecular chemistry;terpyridine