Thin Solid Films, Vol.460, No.1-2, 101-115, 2004
Plasma spraying of nanostructured partially yttria stabilized zirconia powders
Nanosized partially yttria stabilized zirconia particles, prepared using a co-precipitation method, were reprocessed into agglomerate powders using two methods for plasma spraying. The first method was to make micrometer-sized agglomerates directly following the grinding of the calcined yttria-zirconia agglomerates. The second method was to reconstitute the nanosized particles into micrometer agglomerates using spray drying. The deposition efficiency, porosity, microhardness and average grain size of the deposits made from these two reprocessed powders were studied. Distinct results related to the process parameters were obtained for the two types of powders. The second type of powder was more suitable for plasma spraying than the first one. Using the second type of powder, some unique results distinguished from those of the conventional partially yttria stabilized zirconia powders were observed and an optimized coating with a porosity of 3.8%, Hv(0.3) of 953 and mainly consisting of 1-3 mum columnar grains in the columnar direction and smaller than 100 nm in their cross-sections was achieved. (C) 2004 Elsevier B.V. All rights reserved.