Using the doped polymeric system composed of host poly(N-vinylcarbazole) and dopant coumarin 6, the morphology, phase distribution, and polymer molecular conformation of polymer films were investigated with optical and atomic force microscopy, UV-visible absorption spectra, and Fourier transform infrared reflectance spectroscopy. Results show that the film morphology and dopant distribution in the polymer films cast with the conventional method are dependent on the positions of polymer films. To avoid this negative effect, a new spin method was put forward by locating the specimen at an appropriate distance from the center of the spin plate during spin casting. It is found that polymer films prepared with the new method are more uniform and their electroluminescence performances are independent of the positions. (C) 2004 Elsevier B.V All rights reserved.