화학공학소재연구정보센터
AAPG Bulletin, Vol.88, No.3, 325-353, 2004
Hydrocarbon prospectivity of Nigeria's inland basins: From the viewpoint of organic geochemistry and organic petrology
The inland basins of Nigeria comprise the Anambra basin, the lower, middle, and upper Benue trough, the southeastern sector of the Chad basin, the Mid-Niger (Bida) basin, and the Sokoto basin. Organic geochernical and organic petrologic studies indicate that coal beds constitute major potential source rocks in the whole of the Benue trough (Anambra basin inclusive). The generation and procluction of liquid and gaseous hydrocarbons from coal beds is presently indisputable worldwide. In the Anambra basin, the coal beds in the Mamu Formation (Campanian-Maastrichtian) have total organic carbon (TOC) contents of as much as 60.8 wt.%, mean hydrogen index (HI) of 3 64 mg HC/g TOC, vitrinite reflectance (R-o) of 0.54-0.56%, and T-max 430-433degreesC. Biomarker data indicate a dominance of high-molecular-weight n-alkanes, very high pristane/phytane ratios, pronounced odd-over-even predominance (OEP), a preponderance Of C-29 regular steranes, and relatively high contents Of C-28. In the middle Benue trough, the coal beds of the Turonian-Coniacian Awgu Formation have TOC contents of as much as 79.1 wt.%, R-o of 0.83-1.07%, and mean HI of 281 mg HC/g TOC, unimodal distributions of both low- and high-molecular-weight n-alkanes with no obvious OEP, a predominance Of C29 steranes, and relatively high contents of C-27 and C-28. Coal beds from the Coniacian-lower Santonian Lamja Formation in the upper Benue trough yielded TOC contents of as much as 50.7 wt.%, with HI of 184 mg HC/g TOC, R-o of 0.70-0.73%, low- and high-molecular-weight n-alkane dominance with an unpronounced OEP, high pristane/phytane ratios, and very high contents Of C29 regular steranes.