Journal of Applied Polymer Science, Vol.94, No.3, 1024-1028, 2004
Properties of silica/clay filled heavy-duty truck tire thread formulation
A tire thread formulation for heavy-duty trucks containing SBR/BR rubber blend and varying proportions of silica/clay fillers including a silane-coupling agent have been investigated. The various mixes were compounded in a Banbury 'O' mixer and vulcanized using the EV-system. Silica/clay (80/0) served as the control mix. The oscillating disc rheometer (ODR) was used in determination of cure characteristics. Substitution of silica (80 phr) with china clay up to 40 phr increased the cure rate of the rubber blend mixes as well as their maximum torque level (T-max). T-max was observed to be highest at a filler blend ratio of 40/40 phr. Synergism between silica and clay at this filler blend mixture is suggested to be responsible for the observation. The heat buildup was reduced from 43 to 20degreesC as the clay content increased. Results also showed that the rubber blend compound containing silica/clay (60/20) filler blend in the stated ratio exhibited the best balance of properties in the critical parameters such as the absolute torque level (69.5 dNm), heat buildup (39degreesC), and abrasion resistance (0.574 mg.loss/1,000 rev). The rate of depreciation of abrasion resistance of rubber blend compound as the clay content increased was found to be 0.035 mg loss/1,000 rev as silica is substituted with one part of china clay phr. (C) 2004 Wiley Periodicals, Inc.