Journal of Chemical Engineering of Japan, Vol.37, No.9, 1172-1178, 2004
Methods for determining the kinetic parameters from nonisothermal thermogravimetry: a comparison of reliability
This paper has presented some popular methods used to determine the kinetic parameters from nonisothermal thermogravimetric analysis (TGA) data. These methods include the improved Doyle-Ozawa method, and the nonlinear regression method. The above-mentioned methods along with a new method proposed by the present authors are compared with the true thermogravimetric data generated by the synthetic TG/DTG curves. This paper has shown that the proposed E-2-function method has the advantages of both reliability in calculation and straightforwardness in formulation.
Keywords:thermogravimetric analysis;Arrhenius equation;E-2-function method;Doyle-Ozawa method;nonlinear regression method