화학공학소재연구정보센터
Journal of Chemical Physics, Vol.121, No.10, 4853-4864, 2004
Polymer adsorption onto random planar surfaces: Interplay of polymer and surface correlations
We study the adsorption of homogeneous or heterogeneous polymers onto heterogeneous planar surfaces with exponentially decaying site-site correlations, using a variational reference system approach. As a main result, we derive simple equations for the adsorption-desorption transition line. We show that it is preferable to have a small amount of strongly adsorbing sites or monomers rather than a greater amount of weakly adsorbing ones. The results are discussed with respect to their implications for the physics of molecular recognition. (C) 2004 American Institute of Physics.