화학공학소재연구정보센터
Journal of Chemical Physics, Vol.121, No.22, 11503-11504, 2004
Comment on: "Disentangling density and temperature effects in the viscous slowing down of glass forming liquids" [J. Chem. Phys. 120, 6135 (2004)]
Recently, Tarjus [G. Tarjus, D. Kivelson, S. Mossa, and C. Alba-Simionesco, J. Chem. Phys. 120, 6135 (2004)] concluded from a review of data for a variety of glass formers that the supercooled dynamics are almost invariably dominated by temperature T, rather than by density rho. By including additional published data into such a compilation, we show that for van der Waals molecular liquids, the dynamics near T-g are in fact governed as much by density as by temperature. Moreover, relaxation times measured at various temperatures and pressures can be superimposed by plotting as a function rho(gamma)/T. This scaling form can arise from an assumed inverse power law for the intermolecular repulsive potential, with gamma a material constant. (C) 2004 American Institute of Physics.