Journal of Colloid and Interface Science, Vol.280, No.1, 83-90, 2004
Two-dimensional Monte Carlo simulations of a polydisperse colloidal dispersion composed of ferromagnetic particles for the case of no external magnetic field
We have investiated the aggregation phenomena in a polydisperse colloidal dispersion composed of ferromagnetic particles by means of the cluster-movin Monte Carlo method. The results have been compared with those for a monodispersc system. The internal structures of aggregates have been analyzed in terms of the radial distribution function in order to clarify the quantitative differences in the internal Structures of clusters. In addition, the Cluster size distribution and angular distribution function have been investigated. The results obtained in the present study are summarized as follows. In a monodisperse system, open necklacelike Clusters are formed and they extend with increasing strength of the magnetic particle-particle interaction. In a polydisperse system with a small standard deviation in the particle size distribution, sigma = 0.2, larger necklacelike Clusters are formed and some looplike clusters can also be observed. In a polydisperse system with a larger standard deviation, sigma=0.35, clumplike clusters are formed for a weak magnetic particle-particle interaction. For a stronger magnetic interaction, larger size clusters that exhibit a complicated network Structure are formed. These complicated Cluster formations found in a polydisperse system are mainly due to the effect of the presence of larger particles. (C) 2004 Elsevier Inc. All rights reserved.
Keywords:magnetic fluid;ferromagnetic colloidal dispersion;particle size distribution;aggregation phenomena;Monte Carlo simulation