화학공학소재연구정보센터
Chemical Engineering & Technology, Vol.21, No.12, 954-958, 1998
MAO-free metallocene based catalysts in high pressure polymerization of ethylene and 1-hexene
The high pressure polymerization studies of l-hexene and ethylene without the costly cocatalyst MAO using a MAO-free, activated metallocene dichloride catalyst is presented. The influence of the aluminumalkyl on productivity, the Zr and aluminumalkyl concentrations on molecular weight, and co-monomer concentration on productivity and co-monomer incorporation were studied.