화학공학소재연구정보센터
Journal of Materials Science, Vol.39, No.19, 5925-5937, 2004
Processing, properties and arc jet oxidation of hafnium diboride/silicon carbide ultra high temperature ceramics
The processing and properties of HfB2-20 vol%SiC ultra high temperature ceramics were examined. Dense billets were fabricated by hot-pressing raw powders in a graphite element furnace for 1 h at 2200degreesC. Specimens were then tested for hardness, mechanical strength, thermal properties and oxidation resistance in a simulated re-entry environment. Thermal conductivity of the current materials was found to be less than previous work had determined while the strength was greater. Oxidation testing of two flat-face models was conducted, at two conditions, for two 10-min durations each. It was concluded that passive oxidation of SiC plays a role in determining the steady-state surface temperatures below 1700degreesC. Above 1700degreesC, temperatures are controlled by the properties of a thick HfO2 layer and active oxidation of the SiC phase. (C) 2004 Kluwer Academic Publishers.