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Chemical Engineering and Processing, Vol.33, No.2, 55-59, 1994
Validation of the Gas-Lift Capillary Bubble-Column as a Simulation Device for a Reactor by the Study of CO2 Absorption in Na2Co3/Nahco3 Solutions
Validation of the gas-lift bubble column, a new laboratory device, has been achieved by studying the chemical absorption of carbon dioxide into carbonate/bicarbonate solutions. This reaction has been conducted over a range of temperatures extending from 293.2 K to 343.2 K, and using the hypochlorite ion as a catalyst, with corresponding NaClO molarities ranging from zero to 0.2 M. The Danckwerts model was used. The surface renewal rate s, the liquid-side mass-transfer coefficient kL and the rate constant k2 wer determined. During the hydrodynamic study, the gas-liquid exchange area was evaluated by a photographic method.
Keywords:KINETICS