Municipal grey waste (i.e. the remaining fraction in municipal waste management systems in which putrescibles (biowaste) and other recyclables (paper, metals, glass) are source-segregated) was manually sorted into six main fractions on the basis of composition and also separated by sieving (100 turn mesh size) into two fractions, oversized and undersized, respectively. In practice, in waste management plant the oversized fraction is (or will be) used to produce refuse-derived fuel and the undersized landfilled after biological stabilisation. The methane yields and nitrogen solubilisation of the grey waste and the different fractions (all studied samples were first milled to 5 turn particle samples) were determined in a 237-day methane production batch assay and in a water elution test, respectively. The grey waste was found to contained remnants of putrescibles and also a high amount of other biodegradable waste, including packaging, cartons and cardboard, newsprint, textiles and diapers. These waste fractions comprised 41%-w/w of the grey waste and produced 40-210 m(3) methane (total solids (TS))(-1) and less than 0.01 g NH4-NkgTS(added)(-1) except add diapers which produced 9.8 g NH4-N kg TSadded-1 in the batch assays. In the case of the two sieved fractions and on mass bases, most of the methane originated from the oversized fraction, whereas most of the NH4-N was solublised from the undersized fraction. The first-order kinetic model described rather well the degradation of each grey waste fraction and component, showing the different components to be in the range 0.021-0.058 d(-1), which was around one-sixth of the values reported for the source-segregated putrescible fraction of MSW. (C) 2004 Published by Elsevier Ltd.