화학공학소재연구정보센터
Chemical Engineering Communications, Vol.192, No.3, 336-350, 2005
Application of PSRK for process design
A survey about the current status and potential of the predictive Soave-Redlich-Kwong (PSRK) group contribution equation of state (EoS) is given. The PSRK method combines the SRK EoS with the UNIFAC group contribution model by the PSRK mixing rule. The availability of a large number of interaction parameters between UNIFAC and new PSRK main groups allows calculating the phase equilibrium behavior and other thermodynamic quantities for various kinds of systems even with strong electrolytes. Different fields of application are discussed: the prediction of gas solubilities in asymmetric systems, the air solubility calculated for mixed solvents, the removal of H2S from natural gas by predicting the physical absorption, and the calculation of the enthalpy effects of absorption processes with pressure and temperature.