화학공학소재연구정보센터
Chemical Engineering Science, Vol.59, No.22-23, 4869-4877, 2004
Nonlinear analysis of current instabilities in high temperature fuel cells
The conductivity of electrolytes in high temperature fuel cells increases with increasing temperature. It is shown that this property may lead to instabilities, inhomogeneous temperature fields, and hot spots. A simple spatially one-dimensional model of a cell is studied by phase plane analysis and numerical bifurcation analysis. The operation of the cell at constant voltage and at constant current is considered. It is found that in both cases spatial temperature patterns and channels of high current density can form. (C) 2004 Elsevier Ltd. All rights reserved.