화학공학소재연구정보센터
Journal of Materials Science, Vol.39, No.23, 6987-6991, 2004
Hydriding kinetics of the La1.5Ni0.5Mg17-H system prepared by mechanical alloying
In the study of reaction kinetics between hydrogen and hydriding alloys, what is the most important is to obtain intrinsic kinetic data. The hydriding kinetics of 0.5 g La1.5Ni0.5Mg17 sample in the two-phase (alpha-beta) region was investigated as a function of temperature and pressure in the ranges 553-573 K and 0.256-0.992 MPa H-2 respectively. Mathematical analyses of the time-dependent hydrogen absorption curves indicate agreement with Jander diffusion model, [1 - (1 - xi)(1/3)](2) = k(T, P)t, which suggests that the rate-controlling step for hydrogen absorption is three-dimensional diffusion. An apparent activation energy for such diffusion process of 83 +/- 1 kJ/mol H-2 has been obtained from the absorption data. (C) 2004 Kluwer Academic Publishers.