화학공학소재연구정보센터
Chemical Engineering Communications, Vol.145, 23-32, 1996
Monolithic catalysts : Diffusional mass transfer of CO through y-alumina substrates under reacting conditions
Experimental kinetic data have been obtained for the CO oxidation reaction over laboratory made platina-rhodium monolithic catalyst. Inert layers of gamma-alumina were deposited over the active layer in order to elucidate the diffusional effects on the monolithic catalyst. A synthetic gas mixture consisting of CO, O-2 and N-2 was the feed of an integral tubular reactor between 180 and 370 degrees C. A first order kinetic rate expression with respect to CO concentration, which includes an inhibition term of second order was found to fit the experimental data via a model which also accounts for diffusional resistances. The obtained kinetic and diffusional data can be used in the design of a catalytic converter with improved efficiency. The results can also be used to interpret the diffusion mechanism inside the catalyst itself and it was concluded that Knudsen diffusion mechanism prevails.